黄建滨
现从事表面活性剂溶液及界面物理化学性质的研究。在表面活性剂物理化学,特别是溶液中两亲分子有序组合体的形成、结构与功能方面开展了深入的工作。
个性化签名
- 姓名:黄建滨
- 目前身份:
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学术头衔:
博士生导师
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学科领域:
物理化学
- 研究兴趣:现从事表面活性剂溶液及界面物理化学性质的研究。在表面活性剂物理化学,特别是溶液中两亲分子有序组合体的形成、结构与功能方面开展了深入的工作。
黄建滨1983年进入北京大学学习。1987、1990、1993年 在北京大学化学系获理学学士、硕士、博士学位。1993-1995年 北京大学物理化学研究所进行博士后研究工作。1995年留校工作。现为北京大学教授、博士生导师。化学学院党委副书记。中国胶体及界面学科组副组长。物理化学学报编委、科学通报特邀编辑、日用化学工业编委、精细化工编委。1998年 获北京大学科研优秀奖。2003年获北京大学教学优秀奖。2001年获中国十大优秀博士后奖,2004年获国家杰出青年科学基金资助现从事表面活性剂溶液及界面物理化学性质的研究。在表面活性剂物理化学,特别是溶液中两亲分子有序组合体的形成、结构与功能方面开展了深入的工作。近5年来发表SCI收录文章40余篇。多次承担教育部和国家自然科学基金委的重大、重点及面上项目。目前主持国家杰出青年科学基金项目1项“溶液中两亲分子有序组合体的调控”、主持国家自然基金重点项目1项“新型两亲分子有序组合体的构筑、结构和功能的调控” 主持国家自然科学基金面上项目和教育部博士点项目各一项。
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黄建滨, J.-B. Huang*, R. Yang, B.-Y. Zhu, X. He, H.L. Fu
Colloids and Surfaces A: Physicochemical and Engineering Aspects 174(2000)403-410,-0001,():
-1年11月30日
Vesicle formation, Cationic and anionic surfactant mixture, Non-aqueous solvent
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【期刊论文】Recent advances in organometallic amphiphiles
黄建滨, Wang Chuanzhong, Huang Jianbin, Tang Shihua
Sep. 1, 2001 Vol. 3 No.9 P. 45 Copyright,-0001,():
-1年11月30日
Organometallic amphiphiles are new class of surfactants. Various novel chemical and physical properties of their aggregates, such as selective binding to metal ions, active control of interfacial tension, catalytic behavior and charge transfer, have been widely investigated in recent years. These interesting properties are reviewed in this paper.
Organometallic amphiphile,, Surfactant,, Aggregation
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黄建滨, Jian-bin Huang, Ying Zhu, Bu-yao Zhu, Run-kai Li, and Hong-lan Fu
Journal of Colloid and Interface Science 236, 201-207(2001),-0001,():
-1年11月30日
Spontaneous vesicle formation was observed in aqueous mixtures of partially hydrolyzed polyacrylamide and single-tailed cationic surfactants. The influences of pH, addition of long-chain alcohols, variation of hydrocarbon chain length, and head group size of the cationic surfactants were investigated systematically. It was found that 30-50% hydrolyzed degree of polyacrylamide and cationic surfactants with 10 or 12 methylene groups are suitable for vesicle formation in the mixed aqueous systems at pH 9.2. Addition of long-chain alcohols was found to be helpful for vesicle formation in some cases. The vesicle stability was also investigated at various temperatures and amounts of ethanol addition.
vesicle formation, polymer-surfactant interaction, organized assembly.,
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【期刊论文】Special Surface and Aggregation Behavior of a Novel Amino Acid Amphiphile
黄建滨, Chuanzhong Wang, Jianbin Huang, * Shihua Tang, and Buyao Zhu
Langmuir, Vol. 17, No.21, 2001,-0001,():
-1年11月30日
Anamino acid amphiphile, N-(4-decyloxy-2-hydroxybenzylidene) glycine, wassynthesized. Surface tension measurement, dynamic light scattering, and transmission electron microscopy were used to investigate its surface activity and aggregation in solution. All behavior was sensitive to the pH value of the solution. It was found that these properties occur at pH=12, which is different from the usual situation for carboxylate amphiphiles. The abnormal behavior can be attributed to the formation of a dimeric structure at pH=12.0. Vesicles were found in this kind of system, which are stable even at the concentration of transition metal ions up to 1mM. This phenomenon was attributed to the formation of complexes.
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黄建滨, Min Mao, Jianbin Huang, * Buyao Zhu, and Jianping Ye
J. Phys. Chem. B 2002, 106, 219-225,-0001,():
-1年11月30日
The transition from vesicles to micelles by adding octane into the dodecyl-pyridinium chloride (DPCl)/sodium laurate (SL), and dodecyltrimethylammonium bromide (DTAB)/SL aqueous two-phase systems has been studied. The two-phase systems were transformed into single-phase isotropic solutions with the addition of a certain amount of octane. The results of dynamic light scattering (DLS) demonstrate the decrease of large aggregates (vesicles) and the increase of the small aggregates (spherical micelles) upon octane addition. Such transformation of the surfactant aggregates was also corroborated by the results of time-resolved fluorescence quenching (TRFQ) and viscometry. The change of the phase behavior was discussed on the basis of the interaggregate interactions influenced by the variation of organized assemblies.
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【期刊论文】The Structural Transition of Catanionic Vesicles Induced by Toluene
黄建滨, Min Mao, Jianbin Huang, * Buyao Zhu, Haiqing Yin, and Honglan Fu
Langmuir 2002, 18, 3380-3382,-0001,():
-1年11月30日
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【期刊论文】Binding of aromatic anion amphiphile to phospholipid vesicles: a fluorescence study
黄建滨, Chuanzhong Wang a, Jianbin Huang a, *, Jianping Ye b
Colloids and Surfaces A: Physicochemical and Engineering Aspects 204(2002)125-129,-0001,():
-1年11月30日
The fluorescence properties of an aromatic anion amphiphile, N-(4-decyloxy-2-hydroxy-benzylidene) glycine (C10HG) have been investigated. The fluorescence spectra of C10HG in lipid vesicles showed stronger intensity than that in aqueous solution, which is due to the less polarity of microenvironment in the former case. A blue-shift maximum of C10HG fluorescence spectra caused by the carbonyl and phosphate groups in the membrane lipid was also observed. The fluorescence lifetimes and anisotropy data showed that the C10HG molecule is immobilized in the membrane, and its motion is blocked by phospholipid. Fluorescence quenching suggested that the molecule is embedded but does not penetrate deeply in the bilayer.
Amphiphile, Phospholipid, Fluorescence study
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【期刊论文】Transformation from precipitates to vesicles in mixed cationic and anionic surfactant systems
黄建滨, Chuanzhong Wang, Shihua Tang, Jianbin Huang, Xinran Zhang, Honglan Fu
Colloid Polym Sci(2002)280: 770-774,-0001,():
-1年11月30日
Self-organized assemblies in easily precipitated mixed surfactant systems [CmH2m+1N (CH3)3BrC12H25SO4Na m=8, 12, CnH2n+1NH2
Surfactants
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【期刊论文】Two-Phase Region in the DTAB/SL Mixed Surfactant System
黄建滨, Haiqing Yin, Min Mao, Jianbin Huang, * and Honglan Fu
Langmuir 2002, 18, 9198-9203,-0001,():
-1年11月30日
The phase behavior as well as the microstructures of the dodecyltrimethylammonium bromide (DTAB)/sodium laurate (SL) aqueous two-phase system has been studied. ByusingFF-TEM, dynamic light scattering (DLS), a viscosity meter, and polarization microscopy, the effects of surfactant concentration and mixing ratio, temperature, salt concentration, and additives (octanol and toluene) on the phase separation have been systematically investigated. The phase separation is found to be strongly dependent on the variation of the surfactant aggregates. The different kinds of aqueous surfactant two-phase system can transit between each other upon the variation of the mixing ratio, the change of the salt concentration, and the addition of toluene and octanol.
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【期刊论文】Surface properties of bolaamphiphiles in ethanol/water mixed solutions
黄建滨, Feng Han, Jianbin Huang*, Bin Zheng, Zichen Li
Colloids and Surfaces A: Physicochem. Eng. Aspects 242(2004)115-122,-0001,():
-1年11月30日
The effect of ethanol on the surface properties of bolaamphiphiles and their mixed systems with oppositely charged conventional surfactants is studied and compared with the corresponding conventional surfactant systems. It is found that both the bolaamphiphile and the conventional surfactant have the similar variation tendency of γcmc and Γ∞ in the single surfactant system. However, in the cationic and anionic mixed surfactants system the γcmc decreases with the ethanol addition in the bolaamphiphile systems. This tendency is reverse to that in conventional surfactant system. Surface activity of the asymmetric bolaamphiphiles SHMC decreases greatly when ethanol is added into the system due to the existence of the hydroxyl group in the SHMC molecule. Adding opposite charged surfactant may greatly increase surface activity in the SHMC/C12NEt3Br/ethanol systems.
Bolaamphiphile, Surface tension, Micellization, Ethanol-water mixture
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