施宪法
杯芳烃、杯杂芳烃及其衍生物的超分子化学研究。
个性化签名
- 姓名:施宪法
- 目前身份:
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学术头衔:
博士生导师
- 职称:-
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学科领域:
无机化学
- 研究兴趣:杯芳烃、杯杂芳烃及其衍生物的超分子化学研究。
施宪法,浙江绍兴人, 1942年2 月3日出生于四川屏山。中共党员。1963年毕业于南京大学化学系,1966年复旦大学化学系络合物化学专业研究生毕业。1968年-1980年,先后在上海有色金属研究所及上海后方基地群星材料厂(现上海半导体材料厂)工作。1980年1月起在同济大学化学系任教至今。其中1986年11月-1987年10月赴德国布伦瑞克工业大学作访问学者。1984年-1989年任化学系副系主任,1989年-2000年2月任化学系系主任。曾兼任全国高校工科化学课程教学指导委员会委员,上海化学化工学会第六届理事会理事,《同济大学学报》编委等职。现为同济大学化学系教授,博士生导师。
施宪法教授长期从事无机化学、配位化学、微电子材料方面教学与科研工作。曾主持完成国家'八五'科技 攻关项目(子课题),电子工业部及国家教委重点科研项目,及国家自然科学基金项目多项,其中国家'八五'科技攻关项目"TSCE反差增强材料的研制"成果被电子工业部评为"电子行业'八五'国家科技攻关重大成果"。近年来主要研究方向为:杯芳烃、杯杂芳烃及其衍生物的超分子化学研究。这方面的研究先后得到国家自然科学基金和配位化学国家重点实验室基金的多次资助。至今已在国内外重要学术刊物上共发表学术论文七十余篇。获国家专利三个。在教学方面,先后为本科生、研究生主讲"普通化学"、"无机化学"、"配位化学"、"环境健康化学"及"超分子化学"等课程,出版有《普通化学》(同济大学出版社,1993年第一版,1997年第二版)、《化学原理及应用基础o第四分册》(高等教育出版社1999年第一版)等教材。《普通化学》第一、第二版先后两次获同济大学优秀教材一等奖,第二版并获得上海市优秀教材三等奖。由施宪法主编的新编教材《普通化学》已被列入国家'十五'教材规划。现已定稿,定于2004年由高等教育出版社出版。
施宪法教授因出色完成军工配套及'八五'攻关项目,于1995年被国家计委、国防科工委、国家科委和国家经贸委联合授予"国防军工协作配套先进工作者",并于1997年被电子工业部评为电子行业'八五'国家科技攻关先进个人。1995年获宝钢教育奖优秀教师一等奖。1995年和1997年二次被评为上海市教卫系统优秀共产党员。1996年得到国务院政府颁发的特殊津贴。
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20
施宪法, WANG, Lia, ZHENG, Qi-Yu b, CAO, Yan-Yan a, LIU, Yu a, JIANG, Zhong-Liang a, SHI, Xian-Fa, a
CHINESE JOURNAL OF CHEMISTRY 2002, 20, 554-559,-0001,():
-1年11月30日
Several new calixcrowns were synthesized and characterized. The transport of Ca2 + ion was investigated through a bubbling pseudo-emulsion liquid membrane with these calixcrowns, the parent calix [n] arenes (n=4, 6, 8) and the ester, acid derivatives of calix [4] arene as mobile carriers. The effects of the initial concentrations of Ca2 + ion in the source phase and the initial pH difference (ΔpH) between the receiving phase and the source phase were studied. The results suggest that there are two different transport mechanisms. The transports using calixarenes and their ester, acid derivatives as carriers represent a proton-coupled co-transport with a flow of protons in the opposite direction, while the transports using the calix-crowns as carriers exhibit the characteristics of an anion-cou-pled co-transport with a flow of anion in the same direction.
calixarene, calixcrown, Ca2 +, ion, pseudo-emulsion liquid membrane, transport
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施宪法, LI WANG, HONGHAI LI, ZHONGLIANG JIANG, JINYING GU and XIANFA SHI∗
,-0001,():
-1年11月30日
Several new nitrogen-containing calixarene derivatives have been synthesized and their ion-binding properties investigated by UV spectroscopy and solvent extraction. These derivatives include 5,11,17,23-tetra-t-butyl-25,26,27,28-tetrakis (piperidinocarbonylmethoxy) calix [4] arene (5), 5,11,17,23,29,35,41,47-octa-t-butyl-49,50,51,52,53,54,55,56-octa (piperidinocarbonylmethoxy) calix[8]arene (6) and 5,11,17,23,29,35,41,47-octa-t-butyl-49,50,51,52,53,54,55,56-octa(N,N-diethylcarbamoylmethoxy) calix[8]arene (7). The UV spectra of 6 and 7 revealed they had an ability to transform tight lead picrate ion pairs into separated ones by complexation with Pb2+ in tetrahydrofuran. Both derivatives give 1: 1 complexes with Pb2+. Extraction studies showed that these derivatives could efficiently extract Pb2+ (as picrate salts) from the aqueous phase into chloroform. The extractability of these derivatives were also compared with that of the oxygen-containing ester derivative calix [8] arene 2 and the other two nitrogen-containing compounds 8 and 9.
calixarene derivatives,, nitrogen-containing,, lead ions,, ion-binding property,, extraction
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【期刊论文】INTERACTION OF METAL IONS WITH TWO NEW CALIX [4,8] ARENE DERIVATIVES
施宪法, ZHIFENG YE a, WEIJIANG HE a, XIANFA SHI b, and LONGGEN ZHU a, *
J. Coord. Chem., 2001, Vol. 54, pp. 105-116,-0001,():
-1年11月30日
Two new calixarene derivative: 5,11,17,23-tetra-t-butyl-25,26,27,2g-tetrakisa (pipclSdinocarbo-nylmetbyoxy) calix [4] arene (L4) and 5,11,17,23,29,35,41,47-octa-t-butyl-49,50,51,52,53,54,55, 56-octa-(piperidinocarbonylmethoxy) calix [8] arene (L8), which show good binding abilities to metal iota, wen synthesized by the reason of the corespondiog calixarene derivatives with piperidine. The ligand L4 is capable of separating a tight ion-pair foxed by Pb2+ and the picrate anion in THF. The interaction of the new hgands L
Calixarene derivatives, Metal iots, Complexes, EIectrospray mass spectrometry
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【期刊论文】Synthesis and Properties of New Thiacalixarene Derivatives with Palladium Ion
施宪法, ZHI-FENG YE, ZHI-GANG PAN, WEI-JIANG HE, XIAN-FA SHI, and LONG-GEN ZHU, ∗
,-0001,():
-1年11月30日
Three new thiacalix [4] arene derivatives, 5,11,17,23-tetra-tert-butyl-25,27-di (2-hydroxyethoxy)-26,28-dihydroxythiacalix-[4] arene (2), 5,11,17,23-tetra-tert-25, 26,27,28-tetrakis [(methylcarboxyl)methoxy] thiacalix [4] arene (3), 5,11,17,23-tetratert-butyl-25,26,27,28-tetrakis(2-hydroxy-1-propanoxy)thiacalix [4] arene (4), were synthesized for the first time. The coordination properties of thiacalix [4] arene (1) and its derivatives (2and4) were investigated by detecting the interactions between these compounds and two palladium complexes, cis-[Pd(en)(H2O)2]2+ and cis-[Pd(dtco-3-OH)(H2O)2]2+, by means of electrospray ionization mass spectrometry (ESI-MS) technique.
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施宪法, Zhifeng Ye a, Shufeng Pang a, Weijiang He a, Xianfa Shi b, *, Zijian Guo a, Longgen Zhu a
Spectrochimica Acta Part A 57(2001)1443-1447,-0001,():
-1年11月30日
The monolayer properties of p-tert-butylthiacalix[4]arene (TCA) at the air-water interface was investigated by the measurements of surface pressure-area isotherms. However, TCA only exists as a trimmer aggregate on the subphase of deionized water. Copper (II) ion in the subphase can induce the monolayer formation of TCA. The UV-Vis spectra and FTIR spectra of the transferred films suggested that the monolayer formation was fulfilled through the coordination of copper (II) ion to TCA at the air-water surface.
p-tert-Butylthiacalix [4] arene, Monolayer film, Langmuir-Blodgett film
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施宪法, Wang Li, Sun Hongbao, Fu Haiying, Jiang Zhongliang, Shi Xianfa
,-0001,():
-1年11月30日
The transport of Fe3+ ions with p-tert-butyl calix[n]arenes and their derivatives as carriers was studied by means of a bubbling pseudo-emulsion liquid membrane. The factors affecting the transport and the selective transport for Fe3+ ions from a mixture of Fe3+ and Cu2+ ions were investigated. It has been discovered that the gradient of the acidity between the source phase and the receiving phase is the driving force for the transport. Additionally, the transports using a series of calixarenes and their derivatives as carriers were studied and compared with each other. A preliminary discussion for the transport mechanism was also given in this paper.
calixarenes, pseudo-emulsion liquid membrane, Fe3+, ions, transport
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施宪法, Z.F. Ye b, Y.P. Wang a, Y.S. Liu a, Z.L. Jiang a, X. Shen a, L.G. Zhu b, X.F. Shi a, *
Journal of Membrane Science 163(1999)367-372,-0001,():
-1年11月30日
The liquid membrane transport of Na+ ions by p-tert-butylcalix [6] arene and that of K+ ions by p-tert-butylcalix [8] arene were investigated by means of a bubbling pseudo-emulsion liquid membrane system. This system represents a proton-coupled transport with a flow of protons in the opposite direction. The driving force for the transport is the pH gradient between the source and receiving phases. When the pH difference between the two phases is sufficient, the carriers calix [6] arene(or calix [8] arene) can successfully transport Na+ (or K+) ions from the source phase with a lower Na+ (or K+) oncentration into the receiving phase with a higher Na+ (or K+) concentration, like a Na+ (or K+) ion pump.
p-tert-butylcalixarene, Liquid membrane transport, Proton-coupled transport
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施宪法, 齐永路, 顾金英
,-0001,():
-1年11月30日
通过萃取的方法,详细研究了硫杂杯[4]芳烃在不同pH、不同的摩尔配比的萃取剂及不同浓度铅离子等不同条件下的萃取作用,确定了萃取的最佳条件。为硫杂杯[4]芳烃应用于富集或排除铅离子提供了理论依据。
硫杂杯[4]芳烃, 铅离子, 萃取
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【期刊论文】Metallization of Piezoelectric Ceramic Surfaces
施宪法, By X. Shi, Y. Liu, X. Li. Q. Zheng & J. Fang
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-1年11月30日
This paper reports metallization of PZT (lead zirconate titanate) piezoelectric ceramic surfaces accomplished by an electroless plating process with proper after-treat-ment. With this method, nickel electrodes can be formed on PZT piezoelectric ceramic components used in piezo-electric ceramic wave filters. The main mechanical and electric properties of the piezoelectric ceramic conlpo-nents with this type of plated Ni electrode are as good as, or even better than, those with "fired-on" Ag electrodes. This paper introduces the detailed process of pretreat-ment, electroless plating and after-treatment, and dis-cusses the principles, results and various effective factors in each process, and indicates preferred operating condi-tions and control methods feasible in practical production.
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【期刊论文】Preparation of Calixarene-Containing Polymer with Proton Transport Ability
施宪法, LI WANG, XIANFA SHI, PENGJING JIA, YONG YANG
Journal of Polymer Science: Part A: Polymer Chemistry, Vol. 42, 6259-6266(2004),-0001,():
-1年11月30日
To prepare calixarene-based polymers with proton transport ability, the calix [4] arene derivatives with one polymerizable group at the upper rim were first prepared via selective nitration, amination, and acrylamidation of calix [4] arene. Two methods, solution polymerization and emulsion olymerization, were then employed to carry out the copolymerization of these derivatives with other monomers such as styrene, vinyl acetate, or methyl methacrylate. Transport experiments show that the resulting calixarene-based polymers have a very good ability to transport protons.
polymerizable calixarene derivatives, calixarene-based polymer, proton transport ability
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