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刘昌俊, Ji-Jun Zou, , Yue-ping Zhang, Chang-Jun Liu, Yang Li, and Baldur Eliasson
Plasma Chemistry and Plasma Processing, Vol. 23, No.1, March 2003,-0001,():
-1年11月30日
In this work, starch has been used to enhance the oxygenate formation directly from methane and carbon dioxide using dielectric-barrier discharges (DBDs). The use of starch inhibits the formation of liquid hydrocarbons and significantly increases the selecti
Methane, carbon dioxide, starch, dielectric-barrier discharge, oxygenates.,
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刘昌俊, Chang-Jun Liu, , Bingzhang Xue, Baldur Eliasson, Fei He, Yang Li, and Gen-Hui Xu
Plasma Chemistry and Plasma Processing, Vol. 21, No.3, 2001,-0001,():
-1年11月30日
Experimental in
Methane, carbon dioxide, higher hydrocarbon, dielectric barrier discharge.,
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【期刊论文】PLASMA CO2 REFORMING OF METHANE VIA CORONA DISCHARGES
刘昌俊, Changjun Liu, Genhui Xu
Prepr. Pap.-Am. Chem. Soc., Div. Fuel Chem. 2003, 48 (2), 794,-0001,():
-1年11月30日
A lot of attentions have been recently paid to the CO2 reforming of methane to syngas. A major reason for it is that this reaction can provide us a syngas with a 1/1 ratio of H2 and CO, which is typically suitable for the synthesis of valuable oxygenated chemicals.1 Among the catalysts developed, Al2O3 supported Ni catalysts were extensively investigated due to their relatively high activity and low cost. The major problem for the further practical application of these nickel catalysts is the deactivation of the catalyst, suffered from carbon deposition on the catalyst during reactions. Many investigators are working on the improvement in this nickel catalyst by using the addition of promoters,2, 3 using novel reactor configurations,4 and using different supports.3 In this work, we attempt to use an AC corona discharge plasma for the CO2 reforming of methane to syngas. A stable operation of plasma CO2 reforming of methane has been achieved.
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【期刊论文】DFT Study of Structural and Electronic Properties of PdO/HZSM-5
刘昌俊, Jian-guo Wang and Chang-jun Liu*, Jian-guo Wang and Chang-jun Liu*Zhiping Fang, Yue Liu, and Zhongqi Han
J. Phys. Chem. B 2004, 108, 1653-1659,-0001,():
-1年11月30日
A density functional theory (DFT) study has been conducted to investigate the structural and electronic properties of PdO/HZSM-5 and thereby the relationship between PdO and the acid sites of HZSM-5. Different cluster models of PdO/HZSM-5 based on experimental and theoretical works are presented. The study shows that the local structure of PdO supported on HZSM-5 is very similar to the four-coordinated square planar structure of bulk PdO. This is consistent with the reported EXAFS analysis in the literature. The average distances between the Pd and the four coordinated oxygen atoms obtained by DFT calculations with different cluster models are close to the reported experimental results. The analysis of the Mulliken population and the electron density difference of the cluster models shows that there exists a charge transfer from the four coordinated oxygen atoms to the Pd. The components of the frontier molecular orbital of these cluster models come mainly from the Pd and the four coordinated oxygen atoms. The DFT study confirms that the acid sites in HZSM-5 keep the PdO well dispersed due to the bond interaction between the acidic proton atom and the oxygen atom of PdO. In addition, after the formation of PdOH+, the acidity of HZSM-5 complex remains high or in some instances increases.
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【期刊论文】Floating double probe characteristics of non-thermal plasmas in the presence of zeolite
刘昌俊, Chang-jun Liu a, b, *, Jia-xin Wang c, Kai-lu Yu a, Baldur Eliasson d, Qing Xia b, Bingzhang Xue d, Yu-hang Zhang a
Journal of Electrostatics 54(2002)149-158,-0001,():
-1年11月30日
The combination of catalyst and non-thermal plasmas has led to some unusual chemical behaviors, especially with zeolite catalyst. A mechanism has been proposed to explain the observed interaction between catalyst and non-thermal plasmas. This mechanism includes two aspects: plasma promoted or induced catalysis and catalyst enhanced non-equilibrium of nonthermal plasmas. In this paper, we present some direct experimental evidence for the catalyst (zeolite)-enhanced non-equilibrium of non-thermal plasmas suggesting the use of zeolite increases, significantly, the electron temperature of non-thermal plasmas, while the gas temperature remains unchanged. A floating double-probe characteristic has been utilized to measure the electron temperature. Compared to the case without zeolite, the electron temperature of non-thermal plasmas with Mo-Zn/HZSM-5 increases up to 250%, while, at the same time, the discharge power reduces 58%, compared to that without zeolite. r 2002 Elsevier Science B.V. All rights reserved.
Non-thermal plasma, Glow discharge, Double-probe characteristic, Zeolite, Plasma chemical processing, Langmuir probe
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