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【期刊论文】Physical model for the growth of amorphous carbon nanotubes
赵廷凯, T. K. Zhao, G. M. Li, L. H. Liu, Y. N. Liu, and T. H. Li
APL,-0001,():
-1年11月30日
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赵廷凯, 柳永宁, 朱杰武
科学通报2004年12月第49卷第23期,-0001,():
-1年11月30日
采用温控电弧装置,以Co, Ni 合金粉未作为崔化剂,放电电流为80A,电压为32V,放电时间为5min,研究了不同气氛、压力及温度对制取非晶碳纳米管的影响,确定了优化参数。在环境温度为600°C时,氢气气氛,真空度约为6.6×104 Pa,非晶碳纳米管的产量和纯度质量分数都分别达到了6.5g/h和80%以上,其管径为7~20nm.
非晶碳纳米管, 温控电弧法, 气氛影响, 压力影响
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赵廷凯, Peng Zhang, Xuedong Wei, Yongning Liu, Jiewu Zhu, Zhanling Zhang, Tingkai Zhao
Journal of Alloys and Compounds 399 (2005) 270-275,-0001,():
-1年11月30日
Two non-stoichiometric low-Co AB5 alloys, Ml0.95Mg0.05Ni3.8Co0.3Mn0.3Al0.4 (AB4.8) and Ml0.95Mg0.05Ni3.6Co0.3Mn0.3Al0.4 (AB4.6), were designed to reduce the cost ofAB5 alloys. The maximum discharge capacities of the two low-Co alloys can reach 307 mAh/g forAB4.8 alloy and 298 mAh/g for AB4.6 alloy, respectively. After 300 cycles, the capacity decay is 23% for AB4.8 alloy and 19.1% for AB4.6 alloy. XRD patterns and the microstructure, examined by optic microscope and SEM, show that both of the two low-Co alloys are composed of three phases, LaNi5 matrix phase, AlMnNi2 secondary phase and LaNi tertiary phase. For the two low-Co alloys, the microhardness (HV) of the secondary phase are only half of that of the matrix phase, which could resist the crack propagating and make the alloys not amenable to pulverization. The small amount of Mg promotes to form the soft secondary phase, which is believed to be the reason for improving the cycling stability.
Hydrogen storage materials, Microstructure, Electrochemical reactions
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赵廷凯, Tingkai Zhao, Yongning Liu, Jiewu Zhu
Carbon 43 (2005) 2907-2912,-0001,():
-1年11月30日
Large amounts of amorphous carbon nanotubes (ACNTs) were prepared with Co–Ni alloy powders as catalyst in hydrogen gas atmosphere by a modified arc discharging furnace which can control temperature during the electric arcing process. The experimental results indicate that the cooperative function of temperature and catalyst plays an important role in the soot production rate and the relative ACNT purity. When temperature increases from 25°C to 700°C, the soot production rate increases from around 1 g/h to 8 g/h, the best relative ACNT purity at 600°C can reach up to 99% compared to the room temperature sample. Without catalyst, only plate graphite is formed at 25°C and very few carbon nanotubes are found when temperature increases to 600°C. TEM, SEM, HRTEM and XRD analysis showed that the as-prepared carbon nanotubes are almost amorphous. The soot production rate is 8 g/h and diameter range of amorphous carbon nanotubes is about 7–20 nm, respectively. © 2005 Elsevier Ltd. All rights reserved.
Carbon nanotubes, Arc discharge, X-ray diffraction
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赵廷凯, Tingkai Zhao, Yongning Liu
Letters to the Editor. Carbon 42 (2004) 2735-2777,-0001,():
-1年11月30日
A., Carbon nanotubes, B., Arc discharge, C., X-ray diffraction,, Raman spectroscopy
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