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【期刊论文】Synthesis and electrochemical properties of mesoporous 4 nickel oxide
阎子峰, Wei Xing a, b, Feng Li a, c, Zi-feng Yan b, G.Q. Lu a, *
Journal of Power Sources xxx(2004)xxx-xxx,-0001,():
-1年11月30日
Mesoporous Ni(OH)2 is synthesized using sodium dodecyl sulfate as a template and urea as a hydrolysis-controlling agent. Mesoporous NiO with a centralized pore-size distribution is obtained by calcining Ni(OH)2 at different temperatures. The BET specific surface area reaches 477.7m2 g?1 for NiO calcined at 250℃. Structure characterizations indicate a good mesoporous structure for the nickel oxide samples. Cyclic voltammetry shows the NiO to have good capacitive behaviour due to its unique mesoporous structure when using a large amount of NiO to fabricate the electrode. Compared with NiO prepared by dip-coating and cathodic precipitation methods, mesoporous NiO with a controlled pore structure can be used in much larger amounts to fabricate electrodes and still maintain a high specific capacitance and good capacitive behaviour.
Mesopore, Nickel oxide, Electrochemical capacitor, Pseudocapacitance
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【期刊论文】Synthesis and Stabilization of Nanocrystalline Zirconia with MSU Mesostructure
阎子峰, X.M. Liu, †, ‡ G.Q. Lu, *, ‡ and Z.F. Yan†, ‡
J. Phys. Chem. B 2004, 108, 15523-15528,-0001,():
-1年11月30日
In the presence of nonionic block-copolymer surfactant, nanocrystalline zirconia particles with MSU mesostructure were synthesized by a novel solid-state reaction route. The zirconia particles possess a nanocrystalline pore wall, which renders higher thermal stability compared to an amorphous framework. To further enhance its stability, laponite, a synthetic clay, was introduced. Laponite acts as an inhibitor to crystal growth and also as a hard template for the mesostructure. High surface area and ordered pore structure were observed in the stabilized zirconia. The results show that the formation of the MSU structure is attributed to reverse hexagonal micelles, which are the products of the cooperative self-assembly of organic and inorganic species in the solid-state synthesis system with crystalline water and hygroscopic water present.
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阎子峰, WEI XING*, †, FENG LI‡, ZI F. YAN*, H.M. CHENG‡ and GAO Q. LU†, §
International Journal of Nanoscience Vol. 3, No.3 (2004)321-329,-0001,():
-1年11月30日
In this work, nanoporous nickel oxide was synthesized using anionic surfactant assembly method. Structure characterizations show that this nickel oxide possesses partlyordered mesoporous structure with nanocrystalline pore wall. The formation mechanism of wormlike nanoporous structure is ascribed to the quasi-reverse micelle system formed by ternary phases of SDS (sodium dodecyl sulfate)/urea/water. Cyclic voltammetry shows that these nickel oxide samples possess both good capacitive behavior due to its unique nanoporous structure and very high specic capacitance due to its high surface area with electrochemical activity.
Nickel oxide, nanoporous, electrochemical capacitor.,
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【期刊论文】Zeolite Membranes for Environmental Separation and Reactions
阎子峰, Wei Xing, Jo
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-1年11月30日
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【期刊论文】Hydrogen Storage by Carbon Nanotubes
阎子峰, R.G. Ding, J.J. Finnerty, Z.H. Zhu, Z.F. Yan, G.Q. Lu
,-0001,():
-1年11月30日
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