中国科技论文在线

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2004年12月30日

【期刊论文】A novel approach to synthesis of tricyclic diterpenoid

潘鑫复， Xuanjia Peng， Xuegong She， Ying Su， Tongxin Wu， and Xinfu Pan*

Tetrahedron Letters 45(2004)3283-285，-0001，（）：

-1年11月30日

摘要

A novel approach has been found and the first total synthesis of (

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2004年12月30日

【期刊论文】The first asymmetric total synthesis of several 3, 4-dihydroxy-2, 2-dimethyl-chroman derivatives

潘鑫复， Qiaoling Wang， Xuegong She， Xinfeng Ren， Junying Ma， and Xinfu Pan*

Tetrahedron: Asymmetry 15(2004)29-34，-0001，（）：

-1年11月30日

摘要

The stereoisomers of 3, 4-dihydroxy-6-methoxy-2, 2-dimethyl-chroman 1a-c and 3, 4, 7-trihydroxy-6-acetyl-2, 2-dimethylchroman 2a-c were conveniently prepared for the first time via a synthesis in which Sharpless asymmetric dihydroxylation and Jacobsen's catalytic asymmetric epoxidation are the key steps.

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2004年12月30日

【期刊论文】First enantioselective synthesis of daphneticin and its regioisomer

潘鑫复， Xinfeng Ren， Xiaochuan Chen， Kun Peng， Xingang Xie， Yamu Xia， and Xinfu Pan*

Tetrahedron: Asymmetry 13(2002)1799-804，-0001，（）：

-1年11月30日

摘要

An enantioselective total synthesis of chiral daphneticin and its regioisomer is reported for the first time.

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2004年12月30日

【期刊论文】The synthesis of new optically active 2-methylquinoline derivatives and their application in the enantioselective addition of diethylzinc to aldehydes

潘鑫复， Qianyong Xu， a， Guoxing Wang， Xinfu Pana， *， and Albert S. C. Chanb

Tetrahedron: Asymmetry 12(2001)381-385，-0001，（）：

-1年11月30日

摘要

Homochiral 2-methylquinoline derivatives have been synthesized and applied in the enantioselective addition of diethylzinc to aldehydes. Good yields and enantiomeric excesses of up to 91.4% were observed in these reactions.

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2004年12月30日

【期刊论文】Synthesis of C-7 oxidized abietane diterpenes from racemic ferruginyl methyl ether

潘鑫复， Anpai Li， Xuegong She， Jiyong Zhang， Tongxing Wu， and Xinfu Pan*

Tetrahedron 59(2003)5737-5741，-0001，（）：

-1年11月30日

摘要

A series of naturally occurring C-7 oxidized abietane diterpenes have been synthesized from racemic ferruginyl methyl ether in high yields. 6-Hydroxy1-5, 6-dehydrosugiol (7) can be converted into stable xanthoperol (12) using high temperature. Among the products, the structures of sugiyl methyl ether (2) and 6 (-hydroxysugiyl methyl ether (8) were determined by X-ray analysis.

abietane， terpenes and terpenoids， biologically active compounds， X-ray crystal structures.，

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