已为您找到该学者19条结果 成果回收站
【期刊论文】Synthesis and hydrolytic degradation of aliphatic polyesteramides branched by glycerol
刘孝波, Hailian Zhang, , Yi He, Sai Li, Xiaobo Liu
H. Zhang et al. Polymer Degradation and Stability 88 (2005) 309-316,-0001,():
-1年11月30日
A series of branched polyesteramides (PEAs) were synthesized from adipic acid, hexamethylene diamine, 1, 4-butanediol and caprolactam by melt polycondensation using glycerol as branching agent. The obtained copolymers, with glycerol contents of 0-0.9 wt% (LPEA-PEAg10) were characterized by FTIR, 1H NMR, DSC and viscometry. The FTIR and 1H NMR spectra demonstrated the formation of ester and amide bonds. DSC data indicated the melting and crystallization temperatures decrease with increasing glycerol content. Water absorption experiments suggested no distinct difference in hydrophilicity between these branched PEAs. Alkaline hydrolysis of PEA films was conducted in pH 11.0 NaOH solution at 37, 50 or 80
Hydrolytic degradation, Branched polymers, Polyesteramide, Glycerol
-
51浏览
-
0点赞
-
0收藏
-
0分享
-
408下载
-
0
-
引用
刘孝波, Xiaobo Liu, , Yaobang Zou, Wenting Li, Guoping Cao, Wenjin Chen
X. Liu et al. Polymer Degradation and Stability 91 (2006) 3259-3265,-0001,():
-1年11月30日
Poly (D, L-lactide) (PDLLA) degraded at processing temperature under air and nitrogen. A random chain scission model was established and used to determine the activation energy Ea, and FT-IR, 1H and 13C NMR were used to elucidate the degradation behavior under different atmospheres. Results showed that there were two to three stages. The 1st stage was dominated by the oligomers containing carboxylic acid groups and hydroxyl groups, during which oxygen and nitrogen had little effect on the degradation, thus they share similar Ea. When the oligomers were consumed over or evaporated, the 2nd stage began, and oxygen had a promoting effect on the thermo-oxidation process, resulting in the great decrease in Ea. The third stage of PDLLA was observed when it degraded under nitrogen over 200
Thermo-oxidation, Thermal degradation, Kinetics, Poly (, D,, L-lactide),
-
38浏览
-
0点赞
-
0收藏
-
0分享
-
216下载
-
0
-
引用
【期刊论文】Mechanical and thermal properties study of glass fiber reinforced polyarylene ether nitriles
刘孝波, Cao Li, Xiaobo Liu
C. Li, X. Liu. Materials Letters 61 (2007) 2239-2242,-0001,():
-1年11月30日
Glass fiber (GF) reinforced phenolphthalein-based polyarylene ether nitrile composites were prepared through melt blending, and the composites were characterized by various methods to find that both the mechanical and thermal properties of the silane coupling agent treated GF reinforced composites were improved with the increase of GF content. Tensile strength, flexural strength and Izod impact strength got their highest values with GF content at 35 wt.%, 30 wt.% and 25 wt.% respectively. The heat distortion temperature (HDT) of 30 wt.% GF reinforced composite is 284
-
44浏览
-
0点赞
-
0收藏
-
0分享
-
192下载
-
0
-
引用
【期刊论文】Synthesis and properties of phenolphthalein-based polyarylene ether nitrile copolymers
刘孝波, Cao Li, , Yi Gu, Xiaobo Liu
C. Li et al. Materials Letters 60 (2006) 137-141,-0001,():
-1年11月30日
Phenolphthalein-modified polyarylene ether nitrile copolymers were synthesized by nucleophilic substitution reaction of 2,6-difluorobenzonitrile (DFBN) with varying molar ratios of phenolphthalein (PP) and hydroquinone (HQ). The copolymers were chemically and physically characterized to have good thermal and mechanical properties. PP content of the copolymers has influence on glass transition temperature (Tg) as well as decomposition temperature (Tid). Coats–Redfern method was applied to study the thermal decomposition kinetics of the copolymers to predict the lifespan under thermal aging process of the copolymers, the results show that the lifespan increases with increasing PP content. © 2005 Elsevier B.V. All rights reserved.
Polyarylene ether nitrile, Copolymer, Synthesis, Thermal decomposition, Kinetics study
-
34浏览
-
0点赞
-
0收藏
-
0分享
-
162下载
-
0
-
引用
【期刊论文】Thermal behavior of copper powder prepared by hydrothermal treatment
刘孝波, Wencheng Hu, Lin Zhu, Dong Dong, Wei He, Xianzhong Tang, Xiaobo Liu
J. Mater Sci: Mater Electron,-0001,():
-1年11月30日
Copper powder is synthesized by hydrothermal treatment using the copper powder obtained from the chemical reduction method as a precursor. The copper powder is also treated in benzotriazole solution. The powder X-ray diffraction patterns and SEM photomicrographs exhibit that the copper powder possesses perfect crystallinity and narrow size distribution. The thermal behavior of the three kinds of copper powder is evaluated by thermogravimetry and derivative thermogravimetry. Comparing with the sample prepared by means of the chemical reduction method, the copper powder treated under hydrothermal condition displays a peak temperature of the formation of Cu2O shifting from 60.49
-
39浏览
-
0点赞
-
0收藏
-
0分享
-
161下载
-
0
-
引用