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2009年01月25日

【期刊论文】Total concentrations and fractions of Cd, Cr, Pb, Cu, Ni and Zn in sewage sludge from municipal and industrial wastewater treatment plants

王超, Chao Wang, Xin Hu*, Mao-Lin Chen, Yun-Hai Wu

Journal of Hazardous Materials B119(2005)245-249,-0001,():

-1年11月30日

摘要

Heavy metals are one of the important factors that affect the final disposal of sewage sludge. In this paper, the metal mobility and bioavailability of heavy metals in sewage sludge were studied by using Community Bureau of Reference (BCR) sequential extraction procedure to get more information for the reasonable disposal of sludge. Sewage sludge was collected from five municipal wastewater treatment plants and three industrial wastewater treatment plants. The sludge was examined for and the total concentrations and different chemical fractions of Cd, Cr, Pb, Cu, Ni and Zn. The total metal concentrations of heavy metals in sludge varied greatly. The contents of Zn and Cu were the highest, followed by then Cr, Ni and Pb and the content of Cd was the least. There was no significant difference in total metal concentration between municipal and industrial wastewater treatment plants. Fractions extracted by the BCR sequential procedure were acid soluble/exchangeable, reducible and oxidizable fraction. Sludge pH was found to have profound effect on the chemical fractions of heavy metals. Acidic sludges (Xiamen and Jinlin Petrochemical Group Co., wastewater treatment plant) had higher proportion of the acid soluble/exchangeable fractions than in neutral sludge. In neutral sludges, Pb and Cr were principally distributed in between the oxidizable fraction and the residual fraction; Cu was in the oxidizable fraction; Cd mainly in the residual fraction in municipal wastewater treatment plants and had high percentage of acid soluble/exchangeable and reducible fractions in industrial wastewater treatment plants; Ni and Zn had higher percentage in the acid soluble/exchangeable and the oxidizable fraction.

Sewage sludge, Sequential extraction, Fraction, Heavy metals, Wastewater treatment plant

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2009年01月25日

【期刊论文】Modeling of the Mixture of Wastewater Discharged from A Submerged Multiport Diffuser in Nantong Sea-Area

王超, WANG Chao and WANG Pei-fang

China Ocean Engineering, Vol. 19, No.1, pp. 97-110,-0001,():

-1年11月30日

摘要

Laboratory experiments were conducted to investigate the mixture of wastewater discharged from a submerged multiport diffuser in the Nantong sea-area. The process was then simulated with a three-dimensional numerical model. The plane or line patch was used to impose the discharge momentumflux in the near field. A comparison of model simulation with laboratory experiments shows that the proposed model can be used to simulate the shapes of pollution plumes, the distributions of excess concentration, and the velocity induced by a coflowing diffuser in proximity to a shoreline boundary. From the numerical simulation and laboratory experiments, it is recommended that the multiport diffuser be placed in a hydrodynamically active sea-area.

wastewater discharge, submerged multiport diffuser, three-dimensional numerical model, experiment

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2009年01月25日

【期刊论文】QUANTITATIVE STRUCTURE–BIODEGRADATION RELATIONSHIP STUDY FOR BIODEGRADATION RATES OF SUBSTITUTED BENZENES BY RIVER BACTERIA

王超, GUANG H. LU, *†, CHAO WANG, † and GUO Z. BAO‡

Environmental Toxicology and Chemistry, Vol. 22, No.2, pp. 272-275, 2003,-0001,():

-1年11月30日

摘要

The biodegradation rate constant (K) of 21 substituted phenols, anilines, and benzoic acids was determined by using bacteria from the Songhua River (Jilin Province, China) as an inoculum. All of the compounds studied are readily biodegradable chemicals, as shown by their high K values. The quantitative structure-biodegradation relationship results showed that the biodegradation rate of the studied compounds is related mainly to the heat of formation (Hf) and the negative logarithm of the ionization constant (pKa), whereas no simple relationship exists with the n-octanol-water partition coefficients. The equation K=-1.127

Biodegradation rates Structural parameters Model Prediction

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2009年01月25日

【期刊论文】河道沿岸芦苇带对氨氮的削减特性研究

王超, 王沛芳, 唐劲松, 杨敏

水科学进展,2003,14(3):311~317,-0001,():

-1年11月30日

摘要

氨氮污染已成为我国江河湖库水质下降和水生态系统退化的重要因素之一。借助现场对比观测试验和理论分析的方法,研究不同季节氨氮对河流水质的影响规律,得到了雨洪初期汇流河流水质污染最为严重的结论。系统地研究了沿河岸芦苇带对氨氮的削减净化效应,得到了芦苇带吸附氨氮的主要影响因素为:芦苇生长期、水体污染物浓度、河道流速及气象条件。运用数值模拟和参数优化估算技术,确定氨氮在河道两岸有、无芦苇等植物条件下的衰减系数和削减量,分析了衰减系数的变化规律和削减量大小的影响因素,为河流水生态系统修复和水质预测预报提供科学依据。

河岸芦苇带, 氨氮, 削减特性, 水生态系统, 水体污染

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2009年01月25日

【期刊论文】污染河道对沿岸地下水环境影响规律研究

王超, 李勇, 包振琪

水科学进展,2002,13(5):535~541,-0001,():

-1年11月30日

摘要

以江苏奎河为例,观测研究奎河污染物CODCr、NH+4 -N、NO-3-N、Cl-入渗进入地下水中发生物理、化学及生物变化的时空分布规律,分析河道沿岸土壤对污染物的去除能力。结果表明:河床的土壤对污染物CODCr具有很高的去除率,对NH+4 -N亦有较高的去除率。河道中的NO-3-N在入渗过程中虽有一定的去除率,但由于NH+4-N、NO-2-N等污染因子转化成NO-3 -N,因此该浓度不一定会明显降低。Cl-是保守性污染因子,入渗过程中虽有一定的去除率,但仍对沿岸地下水环境产生影响。因此,当污染河道中污染因子是保守性物质时,必须考虑对沿岸地下水源地的影响。

污染河道, 地下水环境, 现场观测, 去除率

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    河海大学,江苏

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