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【期刊论文】Water Rejective Nature of Fluorinated Microporous Carbon Fibers
李国希, G. Li, †, K. Kaneko, *†, S. Ozeki, F. Okino, *, R. Ishikawa, M. Kanda, * and H. Touhara*
Langmuir 1995,11, 716-717,-0001,():
-1年11月30日
The adsorption isotherms of water and ethanol by fluorinated activated carbon fiber (F-ACF) and ACF were determined. Water was not completely adsorbed by F-ACF until PIP0=0.8, regardless of micropore volume of 0.21 mL g-l, while the water adsorption isotherm of ACF rose steeply above PIP0=0.4. The amount ofwater adsorption by F-ACF at PIP0=0.9 was less than l150 ofthat by ACF. However, the amount of adsorption by F-ACF was more than a halfof that by ACF. Fluorinated carbon micropores were presumed to repel water almost completely without formation of water molecular clusters.
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【期刊论文】Chemisorption and Photoadsorption of NO on Cerium (IV) Oxide
李国希, Guoxi Li, Katsumi Kaneko, and Sumio Ozeki*
Langmuir 1997, 13, 5894-5899,-0001,():
-1年11月30日
CeO2 showed high adsorptivity (4.9 molecules/nm2) for NO at 303 K. The adsorbed species of NO on CeO2 in the dark were the NO dimer and/or dinitrosyl, nitrosyl, and NO2-. About 40% of the NO adsorbed in the dark was chemisorbed mainly as NO2-. N2O seemed to be liberated into a gas phase via the intermediate species, such as the NO dimer. The UV irradiation to CeO2-NO systems at 303K induced the photoadsorption of NO and the photocatalytic formation of N2O. Most of the photoadsorbed species were chemisorbed, mainly as photooxidized species, NO2- and NO3-; all other photoadsorbed species were reversibly adsorbed as nitrosyl and dinitrosyl. A frequency shift was observed in a few IR bands of the adsorbed NO, which might have arisen from the photoreduction of Ce4+ to Ce3+.
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【期刊论文】聚乙二醇在Al2O3/水界面吸附行为的ESR研究
李国希, 邓姝皓, 夏笑虹, 旷亚非, 黄树坤
波谱学杂志,2000,17(6):495-499,-0001,():
-1年11月30日
采用电子自旋共振技术结合自旋标记研究了聚乙二醇在Al2O3/水界面的分子构型和运动行为。结果表明,聚乙二醇在Al2O3上的吸附等温线呈S型,吸附量随聚乙二醇分子量增加而减小,聚乙二醇在Al2O3表面是多点吸附,分子中的大部分链节平躺在Al2O3表面、少部分链节伸向溶液。
吸附, ESR, 聚乙二醇
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【期刊论文】离子注入Mo+或Zr+提高钛在酸性氯化物中的耐蚀性
李国希, 刘晓春, 吴翠兰, 靳九成, 史维东
材料保护,2001,34(10):7-8,-0001,():
-1年11月30日
研究了采用多重能量离子注入Mo+或Zr+的钛在70℃的25%MgCl2+5%NaCl+1.6%HCl溶液中的腐蚀行为。结果表明,钛在注入Mo+或Zr+后,自腐蚀电位大大提高,随时间的变化也显著减小,由活性溶解转变为自钝化状态。离子注入Mo+或Zr+能显著提高钛在酸性氯化物溶液中的耐蚀性;注入Mo+的效果较Zr+的好。钛在离子注入Mo+或Zr+后有高耐蚀性可归结于在试样表面形成了一层完整、致密的钛和钼(或锆)的氧化物膜。
耐蚀性, 酸性氯化物, 钛, 离子注入
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李国希, 金子克美.东原秀和
材料研究学报,2002,16(1):93-98,-0001,():
-1年11月30日
将活性炭纤维(AcF)与氟气反应制备出氟化活性炭纤维(FAcF)。根据将:FAcF与参照试样xPs的对比.碳原子是以sp3杂化轨道同氟原子形成共价键。αs图分析氯吸附等温线的结果表明。ACF氟化后其比表面积和微孔容积都显著降低,微孔宽度基本不变。ACF的水吸附等温线呈V型。而FACF对水的吸附量极小:FACF的傲孔表面具有完美的憎水性和高稳定性乙醇和甲醇在ACF上的吸附等温线是I型。在FACF上接近于I型、但吸附培显著降低。
氟化活性炭纤维, 僧水性, 极性分子, 吸附
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