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2009年06月27日

【期刊论文】The generation and accumulation of natural gas from Yinan 2 gas pool in Kuqa Depression

李贤庆, LI Xianqing, , XIAO Xianming, TANG Yongchun, XIAO Zhongyao, MI Jingkui, LIU Dehan, SHEN Jiagui & LIU Jinzhong

Chinese Science Bulletin 2004 Vol. 49 Supp.1 107-114,-0001,():

-1年11月30日

摘要

By using the methods of hydrocarbon generation kinetics and carbon isotope kinetics, combined with geological background of natural gas pool formation, the generation and accumulation of natural gas from Yinan 2 gas pool was studied in Kuqa Depression of the Tarim Basin. Natural gas of Yinan 2 gas pool is mainly' derived from Middle and Lower Jurassic coal-bearing source rocks, and generally belongs to long time-accumulated gas. It is suggested that Yinan 2 gas is chiefly accumulated in the last 5Ma, its Ro ranges from 1.25% to 1.95%, and the loss rate of natural gas is about 25%-30%. This work not only complements and reduces the deficiency of formation model of natural gas pools which traditionally depends on the matching relation-ships between source rock, reservoir, cap rock, and trap, but also is a useful reference in the study of other gas pools.

natural gas formation,, hydrocarbon generation kinetics,, carbon isotope,, source rock,, Ylnan 2 gas pool,, Kuqa Depression.,

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2009年06月27日

【期刊论文】塔里木盆地库车坳陷烃源岩生成甲烷的动力学参数及其应用

李贤庆, ), 肖贤明), 米敬奎, TANG Yongchun), 肖中尧), 刘德汉), 申家贵), 刘金钟)

地质党报,2005,79(1):133~142,-0001,():

-1年11月30日

摘要

In a thermal simulation experiment of closed-system gold tube-high pressure vessels under a given pressure (50M Pa) and calculation with the specific Kinetics and GOR2Isotope Kinetics softw are's, kinetic parameters of gas generation and methane carbon isotope from Triassic-Jurassic source rock sin the Kuqa dep ression of the Tarim Basin are obtained. The ranges of activation energies of methane paralyzed from Jurassic coal, Jurassic mudstone and Triassic mudstone in the Kuqa Dep ression are 197~268kJömol, 180~260kJ/mol, and 214~289kJ/mol, respectively. The frequency ratios are 5.265×1013/s, 9. 761×1011/s, and 2. 270×1014/s. Th is suggests that there are different activation energies and frequency ratios for methanes generated from Jurassic coal, coal-associated mudstone and T riassic mudstone in the Kuqa Dep ression, and reflect their differences of hydrocarbon generation behaviors. The kinetic parameters of methane carbon isotope are also different in Jurassic coal, Jurassic mudstone and Triassic mudstone. Their average activation energies were 228kJ/mol, 205kJ/mol, and 231kJ/mol, respectively. On the basis of the above research, combined with the geological background, the origin of natural gas in the Yinan-gas pool was further discussed using these kinetic parameters, and its gas accumulation model is thus established. The natural gas of the Yinan 2 gas poolwas primarily derived from Jurassic coal2bearing source rock s at the center of the Yangxia Sag and generally belong to the staged accumulative gas. The Yinan 2 gasw asmainly gathered at 5~0Ma with a Ro range of 1.25%~1. 95% and lost about 25%~ 30%.

烃源岩, 甲烷生成, 碳同位素, 动力学, 库车坳陷, 塔里木盆地

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2009年06月27日

【期刊论文】库车拗陷依南-气藏天然气生成与聚集

李贤庆, , 肖贤明, 唐永春, 肖中尧, 米敬奎, 刘德汉, 申家贵, 刘金钟

科学通报,2004,49(S1):100~106,-0001,():

-1年11月30日

摘要

应用生烃动力学与碳同位素动力学方法,结合天然气藏形成的地质背景,研究了塔里木盆地库车拗陷依南-气藏天然气生成与聚集。依南2气藏天然气主要来源于库车拗陷阳霞凹陷中心中下侏罗统含煤岩系烃源岩,基本上属长期累积聚集气,主要聚集时间为0~5Ma,对应风为1.25%~1.95%天然气散失率为25%-30%.该研究,不仅弥补了传统的依据生、储、盖及圈闭的匹配关系来研究天然气藏形成模式的不足,而且对其他气藏的研究具有借鉴意义。

天然气形成, 生烃动力学, 碳同位素, 烃源岩, 依南2气藏 库车拗陷

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2009年06月27日

【期刊论文】Characteristics of Organic Components in Formation Waters and Their Relations to Natural Gas Reservoirs in Central Ordos Basin*

李贤庆, LI XIANQING, ), HOU DUJ IE), HU GUOYI), LIU CHANGQING), AND TANG YOUJUN)

Vol. 22 No.2 CHINES E JOURNAL OF GEOCHEMIS TRY 2003,-0001,():

-1年11月30日

摘要

Isotachophoresis results indicate that the total concentrations of organic acids in Ordovician formation waters range from 9.17mg/L to 94.49mgPL and are obviously higher than those of Permo-Carboniferous formation waters. But both of them have the same compositional characteristics, i.e., acetic acid > > formic acid > propanoic acid > butanoic acid. The total alkyl phenol contents of Ordovician formation waters range from 0.57mg/L to 4.73mg/L, averaging 1.77mg/L. Among the samples for phenol detection, 47.06% samples contain less than 1.0mg/L, 35.29% samples 1.0-3.0mg/L, and only 17.65% samples more than 3.0mg/L alkyl phenol. The concentrations of organic acids and alkyl phenols in the Majiagou formation waters are of obviously heterogeneous distribution. There are several areas where the concentrations of organic acids and phenols are high in central Ordos Basin. These organic acid and phenol-high areas (organic acids >45mg/L and phenols > 2.0mg/L) are consistent with natural gas reservoir enriched areas in central Ordos Basin.

formation water, organic acid, alkyl phenol, Ordovician, gas reservoir, central Ordos Basin

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2009年06月27日

【期刊论文】鄂尔多斯盆地中部气田天然气混源的地球化学标志与评价

李贤庆, , 胡国艺, 李剑, 张爱云.侯读杰, 唐友军

地球化学,2003,32(3):282~290,-0001,():

-1年11月30日

摘要

Gas sources of Ordovician weathered crust gas reservoirs in Central Gas Field in the Ordos basin are an important problem that has not been completely solved. On the basis of a large number of previous research, geochemical characteristics and indexes of mixed origin natural gases i~om Ordovician weathered crust gas reservoirs in Central Gas Field in the Ordos Basin are systematically studied. The gas sources from this gas field are also discussed through the comprehensive analyses of many indexes. The results demonstrate that natural gases from Ordovician weathered crust reservoirs in Central Gas Field in the Ordos Basin have the characteristics of gas components and isotope compositions of high mature and over-mature dl7 gases. In Central Gas Field in the Ordos Basin, there are both coal-ibrmed gas and oil-type gas, the ibrmer of which comes from Permo-Carborrfierous coal measures and the latter originates from lower Paleozoic marine carbonate. The coal-ibrmed gas is mainly located in the eastern part of Central Gas Field while oil-type gas lies in the northern, western and southern parts of Central Gas Field in the Ordos Basin.

奥陶系风化壳, 天然气藏, 气源, 中部气田, 鄂尔多斯盆地

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    中国矿业大学(北京),北京

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