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苟少华, Hai-Bin Zhua, Zhen-Ya Daib, Wei Huanga, Kai Cuia, Shao-Hua Goua, b, *, Cheng-Jian Zhub
Polyhedron 23(2004)1131-1137,-0001,():
-1年11月30日
Several chiral copper(II) complexes of optically active Schiff bases (R,R)-4a-c, which have central seven-membered chelate rings, have been synthesized and characterized. X-ray single crystal analysis of a typical compound indicated that the complex is monomeric and the geometry around the metal atom is very distorted tetrahedral. All the complexes have been tested as catalysts for asymmetric oxidation of methyl phenyl sulfide. The mechanism of the catalytic reaction in the presence of these complexes has been tentatively elucidated.
Asymmetric oxidation, Chiral copper(, II), complexes, Schiff base, Sulfide, Seven-membered
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【期刊论文】Assembly of Seven Nickel(II) Metals by Chiral, Salen-Type Ligands with μ3-OH Bridges
苟少华, Xuan Xu, [a], Shaohua Gou, *[a], Wei Huang, Yonglin Ma, and Yizhi Li[a]
Eur. J. Inorg. Chem. 2003, 2054-2057,-0001,():
-1年11月30日
A chiral heptanuclear nickel(II) complex [NiII(NiII 2L)3(μ3-OH)2]·3H2O [H4L=(2R,3R)-1,4-bis(3,5-di-tert-butylsalicylideneamino)-2,3-butanediol], containing two μ3-OH bridges, has been prepared and structurally characterized; its thermal and magnetic properties were investigated.
Nickel/, Chirality/, Bridging ligands
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苟少华, Wei Huang, [a], Shaohua Gou, *[a], Huifen Qian, [b], Dahua Hu, Suchada Chantrapromma, [c], Hoong-Kun Fun, and Qingjin Meng[a]
Eur. J. Inorg. Chem. 2003, 947-954,-0001,():
-1年11月30日
Two macrocyclic dinuclear zinc(II) complexes (1a and 1b) have been self-assembled in the presence of pyridine and 2,2 -bipyridine, respectively, to form μ2-OH-bridged bimacrocycles with a Zn4O4 cavity through coordination bonding. The X-ray structural analysis reveals that both compounds {2a: [Zn4La 2(OH)2]2(ClO4)2; 2b: [Zn4Lb 2(OH)2]2(ClO4)2} have an open-mouthed sandwich-like structure with π−π interactions between parts of two phenyl rings to strengthen two hydroxyl groups connecting the metal atoms in the same direction of the macrocycle. Furthermore, nonclassical C−H•••Cl intermolecular interactions have been observed in the crystal of 2b. In addition, the reaction of 1a with quinoline derivatives has yielded novel hydrogen-bond-supported donor-acceptor complexes {3a: [Zn2 La(H2O)2(C10H9N)2](ClO4)2}. The crystallographic study of the complex containing 2-methylquinoline indicates that two 2-methylquinoline molecules are linked to two coordinating water molecules above and below the macrocyclic framework through O−H•••N hydrogen bonds. The 2-methylquinoline plane interacts in a face-to-face fashion with the phenyl ring of adjacent macrocyclic frameworks, forming an ordered arrangement where one macrocycle and two 2-methylquinolines are arrayed alternately with almost the same separation. The interplanar distance mentioned before is ca. 3.6Å.
N,, O ligands/, Macrocycles/, Zinc/, Self-assembly/, Structure elucidation/, Hydrogen bonds
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苟少华, Wei Huanga, Dahua Hua, Shaohua Goua, Suchada Chantraprommab, Hoong-Kun Funb, Yan Xua, Qinjing Menga
Inorganica Chimica Acta 342(2003)9-15,-0001,():
-1年11月30日
Two coordination polymers (2a and 2b) containing dinuclear zinc(II) macrocyclic components have been unexpectedly obtained when pyrazine and 2-methylpyrazine were used to react with dinuclear zinc(II) macrocyclic complexes 1a and 1b, respectively. The X-ray crystal structural study indicated that the coordination environment around each Zn(II) atom in 2 is a five-coordinated distorted pyramid in which the apical position is occupied by a bridging formate anion, unlocalized, in an end to end fashion. The formate group acts as a bidentate bridging ligand to link two adjacent macrocyclic units forming a chain polymer. In addition, Hbonding interactions are observed in the crystal packing of 2a and 2b, which could be described as two-dimensional networks.
Crystal structure, Zinc complexes, Macrocyclic complexes, Coordination polymers, Complexes
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苟少华, Jing-cai Yaoa, b, Wei Huangb, Bin Lib, Shaohua Goub, *, Yan Xub
Inorganic Chemistry Communications 5(2002)711-714,-0001,():
-1年11月30日
The self-assembly assisted by 2,20-bipyridine (2,20-bpy) protected zinc(II) species with 1,2-benzenedicarboxylate (1,2-BDC) has yielded a novel one-dimensional single helical coordination polymer of
Self-assembly, Crystal structure, Zn(, II), complex, Single helix coordination polymer
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