-
71浏览
-
0点赞
-
0收藏
-
0分享
-
0下载
-
0评论
-
引用
期刊论文
Concentration Effect in Solid-State CD Spectra of Chiral Atropisomeric Compounds
New J. Chem.,2011,35(9):1781-1786 | 2011年05月06日 | https://doi.org/10.1039/C1NJ20185A
Atropisomerism is one of the basic concepts in stereochemistry. Chiral crystals of stereochemically labile atropisomers that originated from Mirror Symmetry Breaking (MSB) can only be characterized by solid-state chiroptical techniques. Herein, solid-state circular dichroism and UV-Vis spectra of six atropisomeric compounds (most of them were obtained from MSB) have been studied. A concentration effect including a wavelength shift and inverse concentration-dependence has been found and preliminarily explained by the absorption flattening effect, scattering effect and the torsion in the molecular structures.
学者未上传该成果的PDF文件,请等待学者更新
本学者其他成果
同领域成果