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期刊论文
Synthesis of 1,5-regioregular polytriazoles by efficient NMe4OH-mediated azide–alkyne click polymerization
Polym. Chem.，2015，6（31）：5545-5549 | 2015年03月03日 | DOI https://doi.org/10.1039/C5PY00186B
Aromatic alkynes and azides were successfully polymerized under metal-free conditions using tetramethylammonium hydroxide (NMe4OH) as an organocatalyst at room temperature and soluble 1,5-regioregular polytriazoles P3a–P3e with high molecular weights (Mw up to 56 000) were readily produced in high yields (up to 96%).
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