Kinetics of benzene alkylation with 1-dodecene over a supported tungstophosphoric acid catalyst，成果详细信息-中国科技论文在线

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Kinetics of benzene alkylation with 1-dodecene over a supported tungstophosphoric acid catalyst

陈标华， Jinchang Zhang a ， Biaohua Chen a ， Chengyue Li a ， Zuogang Zhu a ， Langyou Wen b ， Enze Min b

Applied Catalysis A: General 249 (2003) 27-34，-0001，（）：

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摘要/描述

The prepared catalyst of tungstophosphoric acid supported on SiO2 has shown high activity, good selectivity of producing linear alkylbenzene (LAB) and 2-phenyl isomer and sufficient catalytic stability. Kinetics of benzene alkylation with 1-dodecene over this catalyst was investigated in a fixed-bed reactor after eliminating the influence of internal and external transport. Rate models of formation of different isomers of LAB were derived based on some simplifying assumptions. Kinetic parameters were determined.

关键词: Benzene alkylation ， 1-Dodecene ， Tungstophosphoric acid ， Reaction kinetics

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