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陈接胜

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期刊论文

Dual Function of Racemic Isopropanolamine as Solvent and as Template for the Synthesis of a New Layered Aluminophosphate: [NH3CH2CH(OH)CH3]3' Al3P4O16

陈接胜 Hong-Ming Yuan Guang-Shan Zhu Jie-Sheng Chen Wei Chen Guang-Di Yang and Ru-Ren Xu

Journal of Solid State Chemistry 151, 145-149 (2000),-0001,():

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摘要/描述

A new layered aluminophosphate [NH3CH2CH(OH)CH3]3' Al3P4O16 containing a racemic mixture of isopropanolamine has been synthesized using isopropanolamine as the predominant solvent and the template and its structure was determined by means of single-crystal X-ray di4raction. The title compound crystallizes in the trigonal space group R31 with M=689.18, a=13.1068(15) A, c=26.935(4) A, Z=6, V=4007.2(9) A3, R=0.0338, and Rw=0.0982. The structure consists of [Al3P4O16]3- macroanionic sheets with a 4

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