A considerable number of studies have been performed on plants of the Valeriana genus in the family of Valerianaceae. These investigations have yielded iriodoids, sesquiterpenoids, lignans, and alkaloids with pharmacological properties, including sedative, cytotoxic, antitumor, antionxidant, and vasorelaxant activities [1-5]. Valeriana jatamansi JONES, an annual herd distributed in the southwestern area of the people's Republic of China, was known in Chinese folk medicine to have tranquilizing hypnotic and antiviralactivities [6-8]. Previous chemical investigation of V. jatamansi revealed the presence of iriodoids, sesquiterpenoids, and an essential oil [2] [6] [8]. Further investigation of the roots of this plant led now to the isolation of two new iridoid triesters, valeriotriates A (1) and B (2). It is noteworthy that few naturally occurring 6-hydroxy-substituted iridoids were foud in the plants of the genus Valeriana. We herein report the isolation and characterization of 1 and 2.