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期刊论文

On the role of planar chirality: a tunable enantioselectivity in palladium-catalyzed allylic alkylation with planar chiral 1,1A-P,N-ferrocene ligands

邓卫平Wei-Ping Deng Xue-Long Hou* Li-Xin Dai Yi-Hua Yu and Wei Xia

Chem. Commun., 2000, 285-286,-0001,():

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摘要/描述

A series of planar chiral 1,1A-P,N-2A-substituted ferrocene ligands 9-12 and 16, prepared with diastereopurity > 99+1, have been used to examine the role of planar chirality, and significant effects on enantioselectivity as well as the control of absolute configuration in palladium-catalyzed allylic alkylation as a model reaction were observed.

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