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期刊论文

Topography Structure and Scanning Tunneling Spectrum of Nickel()Ⅱ-tetraphenylporphyrin Molecules on Au(111)①

邓文礼WANG Zhou-FengJIANG Zhong-JieQIAN Li-PingWANG XianDENG Wen-Li

结构化学2006年4月第25卷第4期/JIEGOU HUAXUE Chinese J. Struct. Chem. Vol. 25, No. 443-448,-0001,():

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摘要/描述

Scanning tunneling microscopy (STM) and scanning tunneling spectroscopy (STS) ere performed on monolayer film of NiTPP supported on Au(111) under ultrahigh vacuum (UHV) conditions. The constant current STM images show remarkable bias dependence. High resolution STM data clearly show the individual NiTPP molecules and allow easy differentiation between NiTPP and CoTPP reported before. Scanning tunneling spectra, as a function of molecule-tip separation, were acquired over a range of tip motion of 0.42 nm. Spectra do not show the variation in band splitting with tip distance. It appears for molecules such as NiTPP that the average potential at the molecule is essentially the same at the same metal substrate. For molecules of the height of NiTPP, the scanning tunneling spectra should give reliable occupied and unoccupied orbital energies over a wide range of tipmolecule distances.

【免责声明】以下全部内容由[邓文礼]上传于[2007年03月14日 09时04分01秒],版权归原创者所有。本文仅代表作者本人观点,与本网站无关。本网站对文中陈述、观点判断保持中立,不对所包含内容的准确性、可靠性或完整性提供任何明示或暗示的保证。请读者仅作参考,并请自行承担全部责任。

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