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期刊论文

Phase transitions due to polar region structure in disordered ferroelectrics

樊慧庆HUIQING FAN * LINGBING KONG LIANGYING ZHANG XI YAO

JOURNAL OF MATERIALS SCIENCE 34(1999)6143-6149,-0001,():

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摘要/描述

We show clear experimental evidence for two phase transitions in titanium doped lead magnesium niobate compositional disordered ferroelectrics. One is the diffuse phase transition near the temperature of the dielectric permittivity maximum, which is often called the characteristic of relaxor ferroelectrics (relaxors). Another is a first-order transformation from relaxor ferroelectric to normal ferroelectric, corresponding to a zero-field spontaneous polar micro-macrodomain switching. According to X-ray diffraction (XRD) measurements, thermal analysis and transmission electron microscope (TEM) results, a dynamic behavior of polar microregions is necessary to explain the phenomena, which is more similar to a stress induced martensitic transformations form cubically stabilized perovskite parent-phase. It is also observed that the dynamic behavior of polar regions was influenced by the titanium doping.

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【免责声明】以下全部内容由[樊慧庆]上传于[2005年09月29日 17时47分05秒],版权归原创者所有。本文仅代表作者本人观点,与本网站无关。本网站对文中陈述、观点判断保持中立,不对所包含内容的准确性、可靠性或完整性提供任何明示或暗示的保证。请读者仅作参考,并请自行承担全部责任。

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