提示
冯大诚
-
32浏览
-
0点赞
-
0收藏
-
0分享
-
65下载
-
0评论
-
引用
期刊论文
Theoretical study on the one-carbon unit transfer from imidazolinium to 1,2-diaminobenzene
Journal of Molecular Structure (Theochem) 579(2002)235-245，-0001，（）：
One-carbon unit transfer from l-aceyl-3-methylimidazolinium to 1,2-diaminobenzene has been studied using PM3 method. The structures of the intermediates and transition states have been optimized. The results show that there are two pathways to transfer the one-carbon unit, and each pathway consists of six steps. They are the combination of two reactants, proton migration, splitting of five-membered ring, formation of benzimidazole ring, another proton migration and separation of C-N bond. And the proton migrating step is the rate limiting step.
【免责声明】以下全部内容由[冯大诚]上传于[2009年02月20日 12时37分18秒]，版权归原创者所有。本文仅代表作者本人观点，与本网站无关。本网站对文中陈述、观点判断保持中立，不对所包含内容的准确性、可靠性或完整性提供任何明示或暗示的保证。请读者仅作参考，并请自行承担全部责任。
本学者其他成果
同领域成果
