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付贤智

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The gas-phase photocatalytic mineralization benzene on porous titania-based catalysts

付贤智Xianzhi Fu Walter A. Zeltner Marc A. Anderson

X. Fu et al. Applied Catalysis B: Environmental 6 (1995) 209-224,-0001,():

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摘要/描述

Photocatalytic degradation of benzene in oxygen-containing gaseous feed streams was investigated using titania and platinized (0.1 wt.-%) titania photocatalysts. The titania catalyst was synthesized using sol-gel techniques. Results of this study indicate that, when using this particular photocatalyst, benzene was oxidized to carbon dioxide and water without forming any detectable organic reaction products in the reactor effluent, although only some of the benzene reacted. Both the overall conversion of benzene and its mineralization were improved by platinizing the titania. When the titania catalyst was platinized, both photocatalytic and thermocatalytic reactions were promoted. Rates of photocatalytic reactions were significantly enhanced at reaction temperatures between 70 and 90

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