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期刊论文

The activation of benzene molecules by BN nanocrystals

郝霄鹏X.P. Hao a D.L. Cui a* X.Q. Yu a Z.G. Liu b X.G. Xu a Q.L. Wang b M.H. Jiang a

Materials Letters 57(2002)703-707,-0001,():

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摘要/描述

Benzene has been activated by BN nanocrystals at 200 and it takes part in the polymerization reaction at 3-5 atm. The experimental results show that no reaction can be detected when benzene was heated to 200 without BN nanocrystals, whereas when BN was added, benzene can be converted into a series of polymerized products, mainly terphenyl. Moreover, the mechanism of the activation of benzene is briefly discussed on basis of the model of coordination chemistry.

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