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期刊论文
p-Dimethylaminobenzamide as an ICT dual fluorescent neutral receptor for anions under proton coupled electron transfer sensing mechanism
Chemical Physics Letters 355(2002)438-444,-0001,():
The intramolecular charge transfer (ICT) dual fluorescence of p-dimethylaminobenzamide (DMABA) in acetonitrile was found to show highly sensitive response to HSO-4 over several other anions such as H2PO-4, AcO- and ClO-4. In the presence of bisulfate anion the dual fluorescence intensity ratio and the total intensity of DMABA decreased while the dual emission band positions remained unchanged. Absorption titration indicated that a 1:1 hydrogen bonding complex was formed between bisulfate anion and DMABA, which gave a binding constant of 2: 02
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