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Functionalized Single Graphene Sheets Derived from Splitting Graphite Oxide

井新利Hannes C. Schniepp† Je-Luen Li‡ Michael J. McAllister† Hiroaki Sai† Margarita Herrera-Alonso† Douglas H. Adamson§ Robert K. Prud’homme† Roberto Car‡ Dudley A. Saville† and Ilhan A. Aksay*

J. Phys. Chem. B, Vol. 110, No.17, 2006,-0001,():

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摘要/描述

A process is described to produce single sheets of functionalized graphene through thermal exfoliation of graphite oxide. The process yields a wrinkled sheet structure resulting from reaction sites involved in oxidation and reduction processes. The topological features of single sheets, as measured by atomic force microscopy, closely match predictions of first-principles atomistic modeling. Although graphite oxide is an insulator, functionalized graphene produced by this method is electrically conducting.

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