提示
邝小渝
-
72浏览
-
0点赞
-
0收藏
-
0分享
-
152下载
-
0评论
-
引用
期刊论文
Spin-singlet contributions to zero-field splitting of a 3d4 ion at a distorted octahedral site and applications to Cr2+ ions in Rb2CrCl4 and CrF2
J. Phys.: Condens. Matter 18(2006)1705-1713，-0001，（）：
The complete energy matrix including all the spin states is constructed for d4ions in tetragonal symmetry within a strong-field representation. The excitationlevels, fine-structure splitting, and EPR parameters in Rb2CrCl4 and CrF2 arestudied with the energy matrix. The contributions of the spin singlets to zerofieldsplitting (ZFS) are investigated for the first time. The results show thatthe spin-singlet contribution to D is negligible, but the contributions to a and Fcannot be neglected.
【免责声明】以下全部内容由[邝小渝]上传于[2006年11月08日 19时52分36秒]，版权归原创者所有。本文仅代表作者本人观点，与本网站无关。本网站对文中陈述、观点判断保持中立，不对所包含内容的准确性、可靠性或完整性提供任何明示或暗示的保证。请读者仅作参考，并请自行承担全部责任。
本学者其他成果
同领域成果
