This article reviews recent advances in polymer blends and composites from renewable resources, and introduces a number of potential applications for this material class. In order to overcome disadvantages such as poor mechanical properties of polymers from renewable resources, or to offset the high price of synthetic biodegradable polymers, various blends and composites have been developed over the last decade. The progress of blends from three kinds of polymers from renewable resources-(1) natural polymers, such as starch, protein and cellulose; (2) synthetic polymers from natural monomers, such as polylactic acid; and (3) polymers from microbial fermentation, such as polyhydroxybutyrate-are described with an emphasis on potential applications. The hydrophilic character of natural polymers has contributed to the successful development of environmentally friendly composites, as most natural fibers and nanoclays are also hydrophilic in nature. Compatibilizers and the technology of reactive extrusion are used to improve the interfacial adhesion between natural and synthetic polymers.