Two kinds of cadmium sulfide (CdS) particulate films have been generated in situ by exposing stearic acid (SA) Langmuir monolayer at the air-aqueous CdCl2 interface to hydrogen sulficde(H2S) gas: particulate films composed of oriented rodlike nanocrystals (A-type particulate films), and those of dotlike nanocrystals which formed a stripelike domain with straight edges aligned with 6-fold symmetry(B-type particulate fims). The SA-coated CdS particulated films were transferred to a solid substrate and examined by transmission electron microscopy (TEM) and photoacoustic spectroscopy (PAS). The dark field image and the transmission particulte fims in detail. The PAS of the CdS particulate fims coposed of the oriented rodlike nanocrystals shows a new peak at 417.5nm. This peak implies some new physical phenomena corresponding to the oredred alignmert of the semiconductor nanocrystals. which exists in the ordered nanosystems. The novel synthesis method described here leads to the fabricaiton of the highly oriented semiconductor quantum wires and provides a new method to investigate the structure of the Langmuir monolayer at the air-water interface.