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期刊论文

High Temperature XPS/AES Investigation of Mo2La2O3 Cathodes Ⅱ. Variation of Lanthanum During Activation Processes X

聂祚仁NIE Zuo-ren ZUO Tie-yong ZHOU Mei-ling WANG Yi-man WANGJin-shu ZHANGJiu-xing

JOURNAL OF RARE EARTHS, 2000 Vol.18 No.2,-0001,():

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摘要/描述

The changes of the valence state of lanthanum in the Mo-La2O3 model cathode specimens were systemati-cally studied by in-situ XPS/ AES analyses from room temperature to 1550 ℃. The experimental results show that the valence of lanthanum changes during the activation processes. As the temperature increases, the lattice oxygen in La2O3 is dissociated, resulting in partial reduction of the lanthanum to LaOx (x<3/2). In addition, the lan-thanum-rich phase diffuses from bulk into the surface of the sample. The lack of lattice oxygen in this phase has a favorable effect on emission, which leads to a lower work function for the Mo2La2O3 cathode.

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