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期刊论文

Fabrication of Titania Tubules with High Surface Area and Well-Developed Mesostructural Walls by Surfactant-Mediated Templating Method

彭天右Tianyou Peng*‡ Akira Hasegawa‡ Jianrong Qiu§ and Kazuyuki Hirao†§

Chem. Mater. 2003, 15, 2011-2016,-0001,():

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摘要/描述

Titania microtubules with high specific surface areas and well-developed framework mesopores forming the tubular walls by a surfactant-mediated template in the sol-gel process were fabricated in a laurylamine hydrochloride (LAHC)/tetra-n-butyl-orthotitanate (TBOT) system. The outer diameter and the wall thickness of titania microtubules are 2-8 and 0.2-2μm, respectively. The walls of the microtubules consisted of nanochannels with exceptionally uniform pore size. This technique is a convenient and facile procedure for fabricating hierarchical ordered hollow tubules. The possible mechanism of the formation of the microtubules in the present system was discussed in detail.

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