-
23浏览
-
0点赞
-
0收藏
-
0分享
-
235下载
-
0评论
-
引用
期刊论文
Synthesis, Characterization, and Magnetic Properties of Intercalation Compound of 1,10-Phenanthroline with Layered MnPS3
Journal of Solid State Chemistry 150, 281-285 (2000),-0001,():
A new intercalation compound Mn0.84PS3(phen)0.64 (phen5 1,10-phenanthroline) was synthesized in one step by direct reaction of host MnPS3 with 1,10-phenanthroline, which was characterized by elemental analysis, X-ray powder di4raction, and infrared spectroscopy. As a result of intercalation, the lattice spacing of the intercalate expanded by 8.63 A with respect to the pristine MnPS3. For comparison, another new intercalation compound Mn0.88PS3[Mn(phen)4]0.12(H2O) was also prepared in two steps by means of ion exchange. The studies of magnetic properties with SQUID-magnetometer indicated that the two intercalates, Mn0.84PS3(phen)0.64 and Mn0.88PS3[Mn(phen)4]0.12 (H2O), exhibit bulk spontaneous magnetization below 36 and 33 K, respectively.
【免责声明】以下全部内容由[秦金贵]上传于[2005年03月07日 19时01分07秒],版权归原创者所有。本文仅代表作者本人观点,与本网站无关。本网站对文中陈述、观点判断保持中立,不对所包含内容的准确性、可靠性或完整性提供任何明示或暗示的保证。请读者仅作参考,并请自行承担全部责任。
本学者其他成果
同领域成果