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Orientation Change of Adsorbed Pyrazine on Roughened Rhodium Electrodes as Probed bySurface-Enhanced Raman Spectroscopy
J. Phys. Chem. B 2005, 109, 17597-17602，-0001，（）：
A surface-enhanced Raman spectroscopic (SERS) study of pyrazine adsorbed on roughened Rh electrodeswas performed. Potential and concentration effects on the adsorption behavior of pyrazine were investigated.The SER spectra display four pairs of overlapping bands with the relative intensity of each pair being highlypotential dependent, which has not been observed on other metals. The orientation change of the adsorbedpyrazine from the end-on to N/
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