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Transport of Na+, K+ ions in a bubbling pseudo-emulsion liquid membrane system with p-tert-butylcalixarenes as carriers

施宪法Z.F. Ye b Y.P. Wang a Y.S. Liu a Z.L. Jiang a X. Shen a L.G. Zhu b X.F. Shi a*

Journal of Membrane Science 163(1999)367-372,-0001,():

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摘要/描述

The liquid membrane transport of Na+ ions by p-tert-butylcalix [6] arene and that of K+ ions by p-tert-butylcalix [8] arene were investigated by means of a bubbling pseudo-emulsion liquid membrane system. This system represents a proton-coupled transport with a flow of protons in the opposite direction. The driving force for the transport is the pH gradient between the source and receiving phases. When the pH difference between the two phases is sufficient, the carriers calix [6] arene(or calix [8] arene) can successfully transport Na+ (or K+) ions from the source phase with a lower Na+ (or K+) oncentration into the receiving phase with a higher Na+ (or K+) concentration, like a Na+ (or K+) ion pump.

【免责声明】以下全部内容由[施宪法]上传于[2005年10月31日 19时29分24秒],版权归原创者所有。本文仅代表作者本人观点,与本网站无关。本网站对文中陈述、观点判断保持中立,不对所包含内容的准确性、可靠性或完整性提供任何明示或暗示的保证。请读者仅作参考,并请自行承担全部责任。

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