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苏成勇

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Multidimensional Frameworks Assembled from Silver(I) Coordination Polymers Containing Flexible Bis(thioquinolyl) Ligands: Role of the Intra- and Intermolecular Aromatic Stacking Interactions

苏成勇Chun-Long Chen† Cheng-Yong Su*† Yue-Peng Cai† Hua-Xin Zhang† An-Wu Xu† Bei-Sheng Kang‡ and Hans-Conrad zur Loye*§

Inorganic Chemistry, Vol. 42, No.12, 2003,-0001,():

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摘要/描述

The two flexible multidentate ligands 1,3-bis(8-thioquinolyl)propane (C3TQ) and 1,4-bis(8-thioquinolyl)butane (C4TQ) were reacted with AgX (X ) CF3SO3 - or ClO4 -) to give four new complexes: {[Ag(C3TQ)](ClO4)}n 1, {[Ag(C3TQ)]- (CF3SO3)}n 2, {[Ag2(C4TQ)(CF3SO3)(CH3CN)](CF3SO3)}n 3, and {[Ag(C4TQ)](ClO4)}n 4. All complexes have been characterized by elemental analysis, IR, and 1H NMR spectroscopy. Single-crystal X-ray analysis showed that chain structures form for all complexes in which the quinoline rings interact via various intra- (1) or intermolecular (2, 3, and 4)

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