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期刊论文

Simple analytic equations of state for hard-core single and double Yukawa fluids and mixtures based on second-order Barker-Henderson perturbation theory

孙久勋Sun Jiuxun

PHYSICA REVIEW E 68, 061503(2003),-0001,():

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摘要/描述

A simple analytic expression with high precision for the radial distribution function of hard spheres is proposed. The form of the expression has been carefully selected to combine the well-known Camahan-Starling equation of state in it and satisfy the limit condition at low density, its simplicity and precision is superior to the well-known Percus-Yevick expression. The coefficients contained in the expression have been determined by fitting the Monte Carlo data for the first coordination shell, and by fitting both the Monte Carlo data and the numerical results of the Percus-Yevick expression for the second coordination shell. The expression has been applied to develop simple analytic equations of state for the hard-core single, double Yukawa fluids, and the hard-core Yukawa mixtures. The comparisons show that the agreement of our model with the computer simulation data is slightly better than the mean spherical approximation and other analytic models.

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【免责声明】以下全部内容由[孙久勋]上传于[2007年09月17日 15时50分30秒],版权归原创者所有。本文仅代表作者本人观点,与本网站无关。本网站对文中陈述、观点判断保持中立,不对所包含内容的准确性、可靠性或完整性提供任何明示或暗示的保证。请读者仅作参考,并请自行承担全部责任。

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