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唐少龙

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期刊论文

Chemical synthesis and magnetic properties of well-coupled FePt/Fe composite nanotubes

唐少龙H LSu S L Tang N J Tang R LWang M Lu and YWD u

INSTITUTE OF PHYSICS PUBLISHING Nanotechnology 16(2005)2124-2128,-0001,():

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摘要/描述

A simple two-step hydrogen reduction method was used to synthesize FePt/Fe composite nanotubes. As the first step, L10 FePt nanotubes were prepared by heating a porous alumina template loaded with an alcohol solution of a Fe chloride and Pt chloride mixture in flowing hydrogen at 670℃. Then, FePt/Fe composite nanotubes were obtained by reducing the alcohol solution of the Fe chloride within the formed FePt nanotubes at a lower temperature, namely 470℃. Through changing the concentrations of initial alcohol solutions, the FePt:Fe atomic ratios of the composite nanotubes were easily adjusted and the magnetic properties were tuned accordingly. For (FePt)100−x /Fex composite nanotubes with x ranging between 0 and 26 at.%, the hard and soft phases were well coupled and the coercivity was tunable over a large range (1.27-2.73 T). Furthermore, the marked interdiffusion between Fe and FePt, which usually exists in FePt-based composites fabricated by using conventional methods, was not observed in the formed composite nanotubes. This indicates the two-step hydrogen reduction method to be a promising route for synthesizing nanocomposites which are difficult to fabricate by using conventional methods due to the interdiffusion between different phase

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