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期刊论文
Size-dependent thermodynamic criterion for the thermal stability of binary immiscible metallic multilayers
Applied Surface Science 252 (2006) 3993-3996，-0001，（）：
With the aim of understanding the thermal stability of binary immiscible metallic multilayers, we propose a generally size-dependent thermodynamic criterion for determining the interface alloying in multilayers, with respect to the size-dependent interface energy of binary metal systems. Taking the copper/tungsten bilayer as an example, we obtain the interfacial alloying phase diagram based on the proposed thermodynamic model. Our theoretical predictions are consistent with experiments, implying that the size-dependent thermodynamic criterion of the thermal stability could be expected to be applicable to many multilayers.
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