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期刊论文
Novel Rearrangement Reactions. 3. Thermal Rearrangement of the Diruthenium Complex (Me2SiSiMe2)[η5-C5H4)Ru(CO)]2(μ-CO)2
Organometallics 1997, 16, 6017-6020，-0001，（）：
The binuclear ruthenium complex (Me2-SiSiMe2)[(η5-C5H4)Ru(CO)]2(μ-CO)2(3) was obtained in poor yield by reaction of Ru3(CO)12 with C5H5Me2-SiSiMe2C5H5 in boiling heptane. A thermal rearrange-ment reaction of 3 in heptane afforded the complex [(Me2Si)(η5-C5H4)Ru(CO)2]2 (4), which was evidently formed via a metathesis between Si-Si and Ru-Ru bonds in 3. Molecular structures of 3 and 4 have been determined by X-ray diffraction.
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