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期刊论文
Synthesis and structures of doubly bridged bis (cyclopentadienyl) terracarbonyl diiron complexes
Journal of Organometallic Chemistry 626(2001)186-191，-0001，（）：
A series of doubly bridged bis(cyclopentadienyl) tetracarbonyl diiron complexes (7-13) have been synthesized by the reaction of the corresponding ligand (1-6) with Fe(CO)5 in refluxing xylene. It is unusual that the reaction of ligand (GeMe2)(GeMe2)(C5H4)2 (3) with Fe(CO)5 gave the complex (GeMe2)[η5-C5H4)Fe(CO)]2(μ-CO)2 (10) as the main product which lost the GeMe2, only a small amount of the expected product (GeMe2)2[(η5-C5H3)Fe(CO)]2(μ-CO)2 (9) was obtained. The molecular structures of 9 and (SiMe2SiMe2)2[(η5-C5H3)Fe(CO)]2(μ-CO)2 (13) have been determined by X-ray diffraction.
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