An RD-space X is a space of homogeneous type in the sense of Coifman and Weiss with the additional property that a reverse doubling property holds in X, or equivalently, that there exists a constant a0 > 1 such that for all x ∈ X and 0 < r < diam (X)=a0, the annulus B(x, a0r) n B(x, r) is nonempty, where diam (X) denotes the diameter of the metric space (X, d). An important class of RD-spaces is provided by Carnot-Caratheodory spaces with a doubling measure. In this paper, the authors introduce some spaces of Lipschitz type on RD-spaces, and discuss their relations with known Besov and Triebel-Lizorkin spaces and various Sobolev spaces.