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引用
期刊论文
The Inhibiting Influence of Aromatic Solvents on the Activity of Asymmetric Hydrogenations**
Angew. Chem. Int. Ed. 2002, 41, No.5，-0001，（）：
Complexes of ruthenium, iridium, and especially rhodium have been used in the homogeneously catalyzed asymmetric hydrogenation of prochiral olefins, ketones, and imines. [1] Hydrogenations are usually carried out in simple alcohols, but aromatic solvents, water, or alcohol/aromatic solvent mixtures can also be used. It has been reported that aromatic solvents such as benzene can inhibit asymmetric hydrogena-phosphatase efficiently and selectively, thereby displaying the fundamental requirements for turnover-based enzyme inactivation.
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