您当前所在位置: 首页 > 学者

张先正

  • 56浏览

  • 0点赞

  • 0收藏

  • 0分享

  • 72下载

  • 0评论

  • 引用

期刊论文

Thermosensitive Poly (N-isopropylacrylamide-co-acrylic acid) Hydrogels with Expanded Network Structures and Improved Oscillating Swelling-Deswelling Properties

张先正Xian-Zheng Zhang† Yi-Yan Yang* Fan-Jing Wang† and Tai-Shung Chung†

Langmuir 2002, 18, 2013-2018,-0001,():

URL:

摘要/描述

In this paper, a P (NIPAAm-co-AAc) hydrogel with rapid temperature sensitivity and improved oscillatory properties over small temperature cycles around the physiologic temperature of 37℃ was synthesized in an alkaline solution (Tris/HCl solution, pH 8.8 and I=0.5M). SEM micrographs revealed that the unique properties achieved can be attributed to the expanded network structure generated in the alkaline solution during the copolymerization reaction. As a result of the dissociation of the carboxyl groups (-COOH) of AAc to carboxylate anions (-COO-), the electrostatic repulsion between carboxylate anions was strong and led to the expanded conformations of polymer chains. Therefore, the network of the hydrogels thus obtained was extremely expanded and exhibited fast temperature sensitivity and improved oscillating swelling-deswelling properties.

关键词:

【免责声明】以下全部内容由[张先正]上传于[2010年07月30日 17时10分39秒],版权归原创者所有。本文仅代表作者本人观点,与本网站无关。本网站对文中陈述、观点判断保持中立,不对所包含内容的准确性、可靠性或完整性提供任何明示或暗示的保证。请读者仅作参考,并请自行承担全部责任。

我要评论

全部评论 0

本学者其他成果

    同领域成果