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郑旭明
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期刊论文
Resonance Raman Study of the Short-Time Photodissociation Dynamics of the A-Band Absorption of Cyclopropyl Iodide in Cyclohexane Solution†
J. Phys. Chem. A 2004, 108, 8032～8039，-0001，（）：
Resonance Raman spectra were obtained for cyclopropyl iodide in cyclohexane solution with excitation wavelengths in resonance with the A-band absorption spectrum. These spectra indicate that the Franck-Condon region photodissociation dynamics have multidimensional character with motion mainly along the nominal C-I stretch and nominal C-C-I deformation normal modes accompanied by moderate motion along the nominal cyclopropyl ring breathing and ring deformation normal modes. A preliminary resonance Raman intensity analysis was done, and the results for cyclopropyl iodide were compared to previously reported results for several cyclic and noncyclic alkyl iodides.
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