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郑旭明
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期刊论文
Resonance Raman Study of Short-Time Photodissociation Dynamics of the Charge-Transfer Band Absorption of Nitrobenzene in Cyclohexane Solution
J. Phys. Chem. A 2005, 109, 3086～3093，-0001，（）：
Resonance Raman spectra were obtained for nitrobenzene in cyclohexane solution with excitation wavelengths in resonance with the charge-transfer (CT) band absorption spectrum. These spectra indicate that the Franck-Condon region photodissociation dynamics have multidimensional character with motion mainly along the nominal NO2 symmetric stretch mode (v11), the nominal benzene ring stretch mode (v7), accompanied by a moderate degree of motion along the nominal ONO symmetry bend/benzene ring stretch mode (v23), the nominal C-N stretch/benzene ring breathing mode (
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