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期刊论文
Reaction of [Et3NH][(m-RE)(m-CO)Fe2(CO)6] (E S, Se) with azides. Synthesis of (m-RE)(m-p-R1C6H4N3H) Fe2(CO)6 and crystal structure of (m-ButS)(m-PhN3H)Fe2(CO)6
Journal of Organometallic Chemistry 601(2000)87-92,-0001,():
The reaction of [Et3NH] [(m-RE)(m-CO)Fe2(CO)6] (E S, Se) (1) with aryl azides gives bridging triazenido complexes (m-RE)(mp-R1C6H4N3H)Fe2(CO)6 (2-8) (2, RE ButS, R1 H; 3, RE PhS, R1 H; 4, RE ButS, R1 Cl; 5, RE ButS, R1 MeO; 6, RE PhS, R1 MeO; 7, RE PhSe, R1 H; 8, RE PhSe, R1 Cl). These complexes were characterized by elemental analyses and 1H-NMR and IR spectroscopy. The structure of complex 2, established by single-crystal X-ray diffraction analysis, shows that the triazenido ligand binds to two iron centers in a bridging bidentate fashion.
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