The contents of soil/sediment organic carbon and clay minerals (i.e. montmorillonite, kaolinite, illite, gibbsite and 1.4nm minerals) for 21 natural soil/sediment samples and the sorption of Triton X-100 on these samples were determined. A multi-component statistic analysis was employed to investigate the importance of soil/sediment organic matters andclay minerals on their sorption of Triton X-100. The sorption power of soil/sediment composition for Triton X-100 conforms to an order of montmorillonite>organic carbon>illite>1.4nm minerals (vermiculite+chlorite+1.4nm intergrade mineral)bkaolinite. The sorption of Triton X-100 on a montmorillonite, a kaolinite anda humic acidwere also investigatedandconsistent with the result of multi-component statistic analysis. It is clear that the sorption of Triton X-100 on soils or sediments is the combined contribution of soil/sediment organic matters and clay minerals, which depended on both the contents of soil/sediment organic matters and the types and contents of clay minerals. The important influence of illite on the sorption of nonionic surfactants onto soils/sediments is suggested and demonstrated in this paper. Surfactants for aquifer remediation application may be more efficient for the contaminated soils/sediments that contain little clay minerals with 2:1 structure because of the less sorption of nonionic surfactants on these soils/sediments.