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2010年07月29日

【期刊论文】From Controllable Attached Isolation Moieties to Possibly Highly Efficient Nonlinear Optical Main-Chain Polyurethanes Containing Indole-Based Chromophores

李振, Qianqian Li, † Zhen Li, *, † Fanxin Zeng, † Wei Gong, † Zhong'an Li, † Zhichao Zhu, † Qi Zeng, † Shanshan Yu, † Cheng Ye, ‡ and Jingui Qin*, †

J. Phys. Chem. B 2007, 111, 508-514,-0001,():

-1年11月30日

摘要

For the first time, the indole-based NLO chromophores were embedded into the polymer main chain, and different isolation groups were attached to their donor side with the efforts of adjusting the NLO properties of the resultant main-chain polyurethanes, according to the site isolation principle. Thanks to the main-chain structure and the advantages of the indole-based chromophores, all the polymers show excellent transparency, good processability, thermal stability, and relatively good NLO effects. The tested NLO properties of the polymers demonstrate that there is a suitable isolation group present for the sulfonyl-based chromophore to boost its microscopic â value to a possibly higher macroscopic NLO property efficiently.

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2010年07月29日

【期刊论文】Convenient Attachment of Highly Polar Azo Chromophore Moieties to Disubstituted Polyacetylene through Polymer Reactions by Using "Click" Chemistry

李振, Qi Zeng, † Zhong'an Li, † Zhen Li, *, † Cheng Ye, ‡ Jingui Qin, † and Ben Zhong Tang*, §

Macromolecules 2007, 40, 5634-5637,-0001,():

-1年11月30日

摘要

Department of Chemistry, Hubei Key Lab on Organic and Polymeric Opto-Electronic Materials, Wuhan UniVersity, Wuhan 430072, China, Organic Solids Laboratories, Institute of Chemistry, The Chinese Academy of Sciences, Beijing 100080, China, and Department of Chemistry, The Hong Kong UniVersity of Science & Technology, Clear Water Bay, Kowloon, Hong Kong

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2010年07月29日

【期刊论文】An Attempt To Modify Nonlinear Optical Effects of Polyurethanes by Adjusting the Structure of theChromophore Moieties at the Molecular Level Using “Click” Chemistry

李振, Zhong’an Li, † Qi Zeng, † Zhen Li, *, † Shoucheng Dong, † Zhichao Zhu, † Qianqian Li, † Cheng Ye, ‡ Chong’an Di, ‡ Yunqi Liu, ‡ and Jingui Qin*, †

Macromolecules 2006, 39, 8544-8546,-0001,():

-1年11月30日

摘要

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2010年07月29日

【期刊论文】Structural Control of the Side-Chain Chromophores To Achieve Highly Efficient Nonlinear Optical Polyurethanes

李振, Zhong'an Li, † Zhen Li, *, † Chong'an Di, ‡ Zhichao Zhu, † Qianqian Li, † Qi Zeng, † Kai Zhang, † Yunqi Liu, ‡ Cheng Ye, ‡ and Jingui Qin*, †

Macromolecules 2006, 39, 6951-6961,-0001,():

-1年11月30日

摘要

Two series of polyurethanes (P1-P10) containing NLO chromophores as side chains were prepared, in which the size of isolation groups was changed from small atoms to much larger groups such as carbazolyl groups. The polymers were well characterized. The tested NLO properties of the polymers demonstrate that the NLO values and the poling efficiency of the polymers are not always improved with increasing of the size of isolation spacer, and for a given chromophore moiety, there is a suitable isolation group present to boost its microscopic â value to possibly higher macroscopic NLO property efficiently.

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2010年07月29日

【期刊论文】Synthesis and Characterization of Indole-Containing Chromophores for Second-Order Nonlinear Optics

李振, Wei Gong, † Qianqian Li, † Zhen Li, *, † Changgui Lu, ‡ Jing Zhu, ‡ Sueyue Li, † Junwei Yang, † Yiping Cui, ‡ and Jingui Qin*, †

J. Phys. Chem. B 2006, 110, 10241-10247,-0001,():

-1年11月30日

摘要

XPush-pull indole-containing nonlinear optical chromophores with different acceptor and ð-conjugated moieties have been synthesized and characterized. Experimental measurements of the second-order nonlinear optical response demonstrated that the chromophores exhibit similar or superior optical nonlinearity compared with their analogues with an aniline moiety as the donor group, but the indole-based chromophores display blueshifted absorption, even up to 30 nm.

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    武汉大学,湖北

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