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2009年02月19日

【期刊论文】Geochemical Study of Rare Earth Elements on Four Attapulgite Clay Deposits in Jiangsu and Anhui Provinces, China*

徐晓春, Chen Tianhu, , Xu Xiaochun, Lu Anhuai, Yue Shucang, Wang Jiaquan, Peng Shuchuan

J OURNAL OF RARE EARTHS, Vol. 21, No.4, Aug. 2003,-0001,():

-1年11月30日

摘要

Abstract: This paper discussed in detail about the REE component and the characteristics of the different kinds of attapulgite clay ores as well as basalts, weathered basalts in four localities of attapulgite clay deposits of Jiangsu and Anhui Provinces of China. It is concluded that the half2weathered basalts have not distinct REE fractionation and strong weathered basalts have HREE loss in the process of the basalts weathered to form smectite group minerals. And the lateritic montmorillonite clays that formed from the basalts weathering have a distinct Ce positive anomaly, a little MREE loss and LREE and HREE renew enrichment. That reflects the particular oxidation condition in the Earth's surface and the adsorption of the colloid solution of the lake water in the basin of the continent in the time of the clays formed. The attapulgite clays produced by the reaction between basalts with lake water in the original place of the basin have same REE character-istics as that of the basalts and the weathered basalts. This shows that REE does not transfer heavily in the progressive chemical weathering process. The sedimentary attapulgite clays have also a similar REE component and characteristic parameters to the basalts and the weathered basalts, and have a distinct Eu negative anomaly and a big value of LREE/HREE, which shows that the sedimentary clay came from the weathered basalts, and REE partitioning patterns characters of the clays are controlled by the residual material of the weathered basalts.

geochemistry, attapulgite, basalt, rare earths

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2009年02月19日

【期刊论文】滇西兰坪盆地西缘铜矿床矿物流体包裹体研究

徐晓春, 谢巧勤, 陆三明, 陈天虎, 黄震, 岳书仓

矿物学报,2005,25(2):170~176,-0001,():

-1年11月30日

摘要

滇西兰坪中新生代盆地西缘发育众多的铜多金属矿床,主要以脉状或透镜状赋存于由砂岩、粉砂岩和页岩组成的含盐红色碎屑岩建造中,或产于火山岩中。本文在前人工作基础上,对区域3个代表性矿床进行了系统的矿物流体包裹体地球化学研究,结果表明:区域铜矿床矿物流体包裹体类型简单,以气液两相包裹体和液相包裹体为主;均一温度不高,显示成矿为中低温度;流体包裹体成分显示为Na++(K+)+Ca2++Cl-+SO42-型,表明成矿流体主要是以大气降水补给的热卤水;成矿流体气相组成主要为H2O和CO2,还原性烃类气体的存在并与氧化性气体的反相关关系显示其与盆地有机质的密切关系及在成矿过程中的重要性。结合成矿地质背景及矿物氢氧同位素的分析,认为该带中的矿床地幔物质参与成矿是次要的,成因上应为受深断裂控制的、大气降水补给的热卤水型矿床。

流体包裹体地球化学, 成矿流体, 铜矿床, 兰坪盆地西缘, 云南

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    合肥工业大学,安徽

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