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【期刊论文】Resonance light scattering characters of core-shell structure of Au-Ag nanoparticles
王永昌, Jian Zhu a, ∗, Yongchang Wang a, Liqing Huang a, Yimin Lu b
Physics Letters A 323(2004)455-459,-0001,():
-1年11月30日
Nanoparticles containing gold cores and silver shells have been synthesized via electrochemical method. The resonance light scattering spectrum has been studied at room temperature. Scattering features show two peaks at 370 nm and 570 nm, which result from the scattering of solid silver nanoparticles and silver coated gold nanoparticles, respectively. The calculation results based on quasi-static theory indicate that with the increasing ratio of the core radius to the total radius of the compound nanoparticles, the peak of scattering cross section decreases first then increases and reaches the minimum when the ratio is about 0.5. And meanwhile the scattering peak red shifts nonlinearly. Furthermore, with the increasing dielectric constant of surrounding medium, the scattering peak increases monotonic and red shifts.
Gold, Silver, Core-shell structure, Nanoparticles, Scattering, Quasi-static theory
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【期刊论文】Fluorescence Spectrum Characteristics of Gold Nanorods *
王永昌, ZHU Jian**, WANG Yong-Chang, YAN Shi-Nong
(CHIN. PIIYS. LETT. Vol.21, No.3 (2004) 559,-0001,():
-1年11月30日
Aqueous solutions containing a high yield of suspended gold nanorods with mean aspect ratio 2.5 have been synthesizeed via an electrochemical method. The fluoresconco emission peaks fixed at 37Onm and 67Onm are due to the local field enhancement via coupling to the transverse and longitudinal urface plasmon resonarce. The qUasi-static calculation results indicate that with the increasing aspect ratio of the nanorods, the longer wavelength emission peak decreases and red shifts, wheresas the shorter wavelenth emission peak blue shifts slightly.
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【期刊论文】Fluorescence spectra characters of silver-coated gold colloidal nanoshells
王永昌, Zhu Jian a, ∗, Wang Yongchang a, Lu Yimin b
Colloids and Surfaces A: Physicochem. Eng. Aspects 232(2004)155-161,-0001,():
-1年11月30日
Aqueous solutions containing a high yield of suspended pure silver, pure gold and silver-coated gold nanoshells have been synthesized via an electrochemical method. UV-vis absorption spectra and fluorescence emission spectra have been measured at room temperature. The absorption spectra show two peaks at 445 and 485 nm, which due to the plasmon resonance of silver-coated gold nanoparticles. Fluorescence emission peaks have been observed in the wavelength region of 550-700nm. The emission peak corresponding to solid silver particles is more intensive than the peaks corresponding to silver-coated gold nanoshells and solid gold particles. The relationship between relative thickness of silver shell and fluorescence intensity has been illuminated from the quasi-static and local field theory. With decreasing the thickness of silver shell, the maximum of local field enhancement factor decrease and red shifts nonlinearly.
Colloidal nanoshells, Plasmon resonance, Fluorescence emission spectra, Absorption spectra, Local field
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【期刊论文】Electrochemical synthesis and fluorescence spectrum properties of silver nanospheres
王永昌, Zhu Jian a, *, Zhu Xiang b, Wang Yongchang a
Microelectronic Engineering 77(2005)58-62,-0001,():
-1年11月30日
Silver colloidal nanospheres have been synthesized via electrochemical method. The absorption spectrum features show two peaks at 410 and 470nm, which result from transverse and longitudinal surface plasmon resonance, respectively. Two kinds of fluorescence emission peaks are observed. The shorter wavelength peaks fixed at about 315nm are due to the local field enhancement and the longer wavelength peaks red shift with the increasing excitation wavelength, which results from the electron interband transitions.
Silver, Nanospheres, Absorption, Fluorescence, Surface plasmon resonance, Local field enhancement
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王永昌, Binghai Yan, Yang Yang, and Yongchang Wang*
J. Phys. Chem. B 2003, 107, 9159,-0001,():
-1年11月30日
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