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2010年01月27日

【期刊论文】Planar chiral 2-ferrocenyloxazolines and 1,1'-bis(oxazolinyl)ferrocenes—syntheses and applications in asymmetric catalysis

邓卫平， Oliver B. Sutcliffe† and Martin R. Bryce*

Tetrahedron: Asymmetry 14(2003)2297-2325，-0001，（）：

-1年11月30日

摘要

The synthesis and reactivity of planar chiral 2-ferrocenyloxazolines and 1,1'bis (oxazolinyl) ferrocenes is reviewed, with particular emphasis on their applications in asymmetric catalysis.

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2010年01月27日

【期刊论文】Syntheses of side-chain fluorinated biologically important imidazoles and indoles

邓卫平， Bohumil Dolensky， Ghilsoo Nam， Wei-Ping Deng， Jayan Narayanan， Junfa Fan， Kenneth L. Kirk*

Journal of Fluorine Chemistry 125(2004)501-508，-0001，（）：

-1年11月30日

摘要

We review in this report the preparation of several side-chain fluorinated analogues of biologically important imidazoles and indoles. The building blocks used should also have applications in other synthetic problems. The addition of "FBr" to vinyl imidazole derivatives was used to prepare b-fluoro- and b,b-difluorohistamine and histidinols, as well as b-fluorourocanic acid. Deoxyfluorination of intermediate acylindoles was used to prepare a series of b,b-difluorotryptamine derivative, including the fluorinated analogue of the important neurotransmitter, serotonin.

Imidazoles， Indoles， Biogenic amines， "， FBr"， addition， Deoxyfluorination

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邓卫平邀请

华东理工大学，上海

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