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2010年05月04日

【期刊论文】Band structure-controlled solid solution of Cd1-x ZnxS photocatalyst for hydrogen production bywater splitting

延卫, Chanjuan Xing, Yaojun Zhang, WeiYan, Liejin Guo*

International Journal of Hydrogen Energy 31 (2006) 2018-2024,-0001,():

-1年11月30日

摘要

A series of Cd1−xZnxS (x=0-0.92) photocatalysts were prepared by coprecipitation method and were calcined at 723K under N2 atmosphere. X-ray diffraction patterns results showed that the solid solution of Cd1-xZnxS were formed between ZnS and CdS. UV-Vis spectra indicated that the absorption edges of Cd1-xZnxS were red-shifted as the value of x decreased. The band gaps of the photocatalysts were estimated to be between 2.20-3.12 eV (x=0-0.92) from the onsets of the absorption edges and almost showed linear variation with x increasing. The position of conduction band for solid solution is shifted towards more negative potential as compared to that of CdS. The hydrogen productions of Cd1-xZnxS (x=0-0.92) by splitting water photocatalytically under ultraviolet and visible light irradiation were carried out in an inner-irradiation type reactor. The results indicated that the photocatalyst of Cd0.62Zn0.16S has the highest rate of hydrogen evolution with the quantum efficiency of 2.17%and 0.60%under ultraviolet and visible light irradiation, respectively. It has been considered that the crystallite size, (101) plane and band gap for the Cd1-xZnxS solid solutions have a strong influence on the efficiency of hydrogen production capability for water splitting.

Cd1−xZnxS solid solution, Photocatalysts, Band gap, Production of hydrogen, Water splitting

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2010年05月04日

【期刊论文】Preparation of PLGA Electrospun Nanofibers for Tissue Engineering Applications*

延卫, DUAN Yuan-yuan, JIA Jun, WANG Shao-hai, YAN Wei, JIN Lei, WANG Zhong-yi

Jan. 2007, Volume 4, No.1 (Serial No.26),-0001,():

-1年11月30日

摘要

Non-woven poly (lactic-co-glycolic acid) (PLGA) nanofibers were prepared by electrospinning technology. The morphology of the electros pun fibers was observed using scanning electron Microscopy (SEM) and the fiber diameter was calculated. Primary human dermal fibroblasts (HDFs) were cultured to evaluate the biocompatibility of the electrospun PLGA nanofibers. The results of MTT testing and SEM showed that the PLGA nanofibers have the morphology of interwoven and highly porous structure and can support the attachment and proliferation of HDFs. It is can be expected to be a potential scaffold material for tissue engineering.

electrospinning, PLGA, tissue engineering

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2010年05月04日

【期刊论文】聚苯胺的合成与聚合机理研究进展

延卫, 徐浩, 冯江涛

化工进展,2008,27(10):1561~1568,-0001,():

-1年11月30日

摘要

近年来,聚苯胺因其优良的性能而备受关注,其合成方法与合成机理一直是聚苯胺研究的重要内容之一.本文详细阐述了聚苯胺的化学和电化学合成方法,并对两类合成方法的反应机理进行了综述。

聚苯胺, 合成方法, 聚合机理

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2010年05月04日

【期刊论文】水系统的积垢及其物理控制技术

延卫, 徐浩, 汤成莉

净水技术,2008,27(3):9-13,-0001,():

-1年11月30日

摘要

主要综述了水系统中水垢的种类、形成机理及其物理防治方法。详细阐述了静电、电子以及磁化等物理控垢法的工行原理技术要点,并指出了其发展方向。

水垢, 形成机理, 物理防治方法

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2010年05月04日

【期刊论文】太阳能光催化分解水制氢体系能量转换效率及量子产率的实验测定与计算

延卫, 张耀君, , 郭烈锦, 赵亮, 杨鸿辉, 李明涛, 许云波

太阳能学报,2006,27(11):1113~1116,-0001,():

-1年11月30日

摘要

对太阳能光催化分解水制氢体系的阈值能、太阳能转换效率以及太阳能转化成可储存的化学能效率进行了阐述;建立了一种利用已知量子产率的化学光量计测定光子数绝对值的实验方法,并使用该方法对太阳能光催化分解水制氢体系的能量转换效率及产氢的量子产率进行子计算。

能量转换效率, 量子产率, 光催化分解水制氢体系

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    西安交通大学,陕西

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